具有柔软排斥性相互作用的结合性颗粒集
Gaoxiang Wu1, Hyesung Cho1, Derek A Wood2
1Department of Materials Science and Engineering, University of Pennsylvania , 3231 Walnut Street, Philadelphia, Pennsylvania 19104, United States.
Journal of the American Chemical Society
|April 4, 2017
概括
我们研究了充电的纳米粒子如何在多孔膜中聚集. 它们的排列对度很敏感,与硬球不同,可以使用静电力来控制.
科学领域:
- 体科学
- 材料科学
- 纳米技术
背景情况:
- 充电的体系统在被封闭的情况下表现出复杂的行为.
- 聚二甲基 (PDMS) 膜为微流体应用提供可调节的多孔结构.
- 静电双层力控制极性介质中的纳米粒子相互作用.
研究的目的:
- 对PDMS膜内的充电纳米粒子组件的微限制效应进行研究.
- 探索纳米粒子度和静电相互作用在组装形态的决定性作用.
- 将实验结果与理论预测和模拟进行比较.
主要方法:
- 在折射率匹配的单体中散射带电的纳米粒子.
- 聚二甲基 (PDMS) 孔隙膜的制造
- 纳米粒子组合的实验观测和特征.
- 使用Yukawa潜力和计算机模拟进行理论建模.
主要成果:
- 观察到不同的纳米粒子组合形态,偏离硬球的行为.
- 组装对散装和局部纳米颗粒度的高度敏感性.
- 发现实验配置与Yukawa的潜在预测一致.
- 用于预测纳米粒子排列的验证模拟模型.
结论:
- 微束和静电力使得富有,可控的纳米粒子组装.
- 纳米粒子度是决定组装结构的关键因素.
- 理论和模拟方法可以准确预测实验结果.
相关概念视频
Intermolecular Forces
62.9K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
62.9K
Intermolecular Forces in Solutions
30.5K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
30.5K
Colloids
17.2K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.2K
Colloids and Suspensions
3.4K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
3.4K
Colloidal precipitates
5.7K
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
5.7K
The Colloidal State
184
The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called...
184


