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相关概念视频

Organic Compounds03:02

Organic Compounds

46.0K
All living things are formed mostly of carbon compounds called organic compounds. The category of organic compounds includes both natural and synthetic compounds that contain carbon. Although a single, precise definition has yet to be identified by the chemistry community, most agree that a defining trait of organic molecules is the presence of carbon as the principal element, bonded to hydrogen and other carbon atoms. However, some carbon-containing compounds such as carbonates, cyanides, and...
46.0K
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

35.5K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
35.5K
Bonding in Metals02:32

Bonding in Metals

45.6K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Coordination Compounds and Nomenclature02:54

Coordination Compounds and Nomenclature

21.1K
In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
21.1K
Structural Isomerism02:34

Structural Isomerism

16.9K
Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly,...
16.9K
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

2.1K
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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Updated: May 5, 2026

Synthesis of a Water-soluble Metal&#8211;Organic Complex Array
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基于盐的共价有机框架

Li-Hua Li1, Xiao-Lin Feng1, Xiao-Hui Cui1

  • 1State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University , Lanzhou, Gansu 730000, China.

Journal of the American Chemical Society
|April 8, 2017
PubMed
概括
此摘要是机器生成的。

研究人员创建了第一个基于Salen的共价有机框架 (COF). 这种稳定的盐COF材料为各种应用的新型金属COF打开了大门.

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科学领域:

  • 协调化学
  • 材料科学
  • 有机化学

背景情况:

  • 盐联体在协调化学中至关重要.
  • 共价有机框架 (COF) 提供可调节的特性.
  • 将连接物整合到COF结构中是一个活跃的研究领域.

研究的目的:

  • 报告基于盐的共价有机框架 (COF) 的首次合成.
  • 展示COF构建和Salen功能化的单步方法.
  • 探索由此产生的Salen-COF的特性和潜在应用.

主要方法:

  • 一个合并COF合成和Salen部分的单步反应.
  • 合成的Salen-COF的结晶性和稳定性的表征.
  • -COF的金属化产生了一系列基于金属的COF.

主要成果:

  • 在单个步骤中成功合成了第一个基于盐的COF (Salen-COF).
  • 由此产生的Salen-COF具有很高的结晶性和很好的稳定性.
  • 通过化成功制备了一系列基于金属的COF.

结论:

  • 开发的单步方法提供了有效的Salen-COF.
  • 萨伦-COF的结构特性使其成为先进材料的有前途平台.
  • 从这项工作中获得的金属COF具有多种应用的潜力.