通过石墨烯进行远程表层,可实现基于材料的二维层转移
Yunjo Kim1, Samuel S Cruz1, Kyusang Lee1
1Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Nature
|April 21, 2017
概括
研究人员表明,范德瓦尔斯的表皮质可能通过石墨烯,使半导体在各种基板上生长. 这种新的方法可以轻松释放涂上石墨烯的基板,使非电子和光学受益.
科学领域:
- 材料科学
- 固态物理
- 表面科学
背景情况:
- 对于半导体来说,Epitaxy至关重要,但通常需要格子匹配.
- 范德瓦尔斯表层使用二维材料来放松格子匹配的约束.
- 之前的理解仅限于德瓦尔斯表层作为种子层的二维材料.
研究的目的:
- 调查二维材料下的基板是否会影响表皮质.
- 通过二维材料层演示远程表轴注册.
- 开发一种使用二维材料转移表层膜的方法.
主要方法:
- 密度函数理论 (DFT) 计算以建模原子-基质相互作用.
- 通过石墨烯对GaAs(001) 的同质增长进行实验验证.
- 使用 (InP) 和 (GaP) 测试该方法.
主要成果:
- 石墨烯的范德瓦尔斯电位不能完全选基质电位,允许远程表轴注册高达9 ångströms.
- 通过单层石墨烯成功增生GaAs,InP和GaP.
- 从石墨烯中快速释放出皮膜,性能与传统的皮膜相提并论.
结论:
- 基质潜能可以通过二维材料调解表,扩大范德瓦尔斯表的可能性.
- 这种技术可以转移各种半导体薄膜,从而促进非设备的制造.
- 石墨烯涂层基板的可重复使用性为先进的电子和光子应用提供了显著的成本节约.
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