有机可充电电池的反氧活性宏循环
Dong Jun Kim1, Keith R Hermann1, Aleksandrs Prokofjevs1
1Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.
Journal of the American Chemical Society
|April 25, 2017
概括
研究人员为可充电电池开发了一种三角形的有机分子, 这一突破解决了有机电池的关键问题,为改进的储能解决方案铺平了道路.
科学领域:
- 材料科学
- 电化学
- 有机化学
背景情况:
- 有机充电电池比离子电池具有成本效益和高容量等优势.
- 一个主要的挑战是控制有机分子的氧化还原潜力以获得稳定的电池电压.
- 目前有机材料往往表现出多个电压平原,限制了它们的性能.
研究的目的:
- 确定一个分子结构,使有机可充电电池具有单一,明确的输出电压.
- 研究分子结构,电子移位和电压概况之间的关系.
- 推进高性能有机电极材料的设计.
主要方法:
- 密度函数理论 (DFT) 计算以模拟电子移位.
- 三角宏环分子,二元和非循环衍生物的合成和电化学表征.
- 包括微分脉冲电量测量,光谱电化学和静态测量的技术.
主要成果:
- 一个三角形的宏循环与三个 pyromellitic diimide (PMDI) 单元表现出一个2.33V的输出电压.
- 在降解和氧化过程中,双环PMDI衍生物表现出多个电压平原.
- 在三角结构中通过空间的电子移位被确定为单个电压配置的关键.
结论:
- 在宏观循环中控制氧化还原活性单元的结构安排对于稳定的电池电压至关重要.
- 三角的宏循环结构促进电子移位,导致可取的单电压高原.
- 这项研究为设计高能量密度和长周期有机电极提供了途径.
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