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Updated: Mar 3, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

Published on: November 22, 2016

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不常见的Pd (III) 氧化状态:具有高导电性和热稳定的Pd-Br链

Mohammad Rasel Mian1, Hiroaki Iguchi1, Shinya Takaishi1

  • 1Department of Chemistry, Graduate School of Science, Tohoku University , 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, Japan.

Journal of the American Chemical Society
|May 4, 2017
PubMed
概括

研究人员开发了一种新型的化链复合物[Pd(dabdOH) 2Br],由于独特的结网,它具有破纪录的电导率和增强的热稳定性.

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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework12:30

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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions11:44

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Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
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