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在气候转变过程中对大气氧化物的多重控制的同位素证据
Lei Geng1,2,3, Lee T Murray4, Loretta J Mickley5
1Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, USA.
Nature
|May 18, 2017
概括
像臭氧 (O3) 和氧 (HOx) 这样的热层氧化剂对大气化学至关重要. 这项研究发现,与以前的假设相反,O3/HOx比率在寒冷气候中增加,这表明了新的气候反机制.
科学领域:
- 大气化学和古气候学
- 研究热层氧化剂及其对气候变化的反应
背景情况:
- 热层氧化剂 (臭氧,基,过氧基) 控制微量气体的寿命和颗粒物形成.
- 目前的理解表明冷气候下降臭氧,HOx相对稳定.
- 在气候转变期间缺乏古记录来限制过去的氧化剂水平.
研究的目的:
- 通过冰核记录调查热层氧化物的过去行为.
- 限制大气氧化剂对过去气候变化的反应.
- 确定与氧化剂化学相关的潜在气候反机制.
主要方法:
- 分析格陵兰冰核中氧气-17过量的酸盐.
- 在最后一个冰川周期和丹斯加德-奥斯格尔事件中重建臭氧/HOx比率.
- 使用冰芯数据作为过去大气氧化剂的代理.
主要成果:
- 在寒冷的气候时期观察到臭氧/HOx比率的增加.
- 这一发现与寒冷气候下降臭氧的普遍假设相矛盾.
- 证据表明,在寒冷的气候中,臭氧和反应性素化学的平流层到热带层的传输得到了增强.
结论:
- 热层氧化剂对气候变化敏感,与当前模型相比,在寒冷的气候中反应反转.
- 从平流层提升臭氧运输和素化学是假设的驱动因素.
- 这些过程可能代表着重要的,未被充分探索的气候反机制.
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