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内分子原子转移在室温的氨基基基中,具有很大的动态同位素效应

Ying Wang1, Arnon Olankitwanit1, Suchada Rajca1

  • 1Department of Chemistry, University of Nebraska , Lincoln, Nebraska 68588-0304, United States.

Journal of the American Chemical Society
|May 19, 2017
PubMed
概括

我们在PEGylated carbazyl基的衰变中观察到显著的动态同位素效应,这表明在原子转移过程中存在量子道. 这种效应在广泛的温度范围内是一致的.

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