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相关概念视频

¹H NMR of Conformationally Flexible Molecules: Temporal Resolution00:52

¹H NMR of Conformationally Flexible Molecules: Temporal Resolution

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At room temperature, the chair conformer of cyclohexane undergoes rapid ring flipping between two equivalent chair conformers at a rate of approximately 105 times per second. These two chair conformers are in equilibrium. The rapid ring flipping results in the interconversion of the axial proton to an equatorial proton and an equatorial to the axial proton. Such interconversions are too rapid and cannot be detected on the NMR timescale. Hence, the NMR spectrometer cannot distinguish between the...
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Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration02:34

Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration

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The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can significantly influence the rate.
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Molecular Shape and Polarity03:37

Molecular Shape and Polarity

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Dipole Moment of a Molecule
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Hydrogen Bonds01:04

Hydrogen Bonds

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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
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Hydrogen Bonds00:26

Hydrogen Bonds

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Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
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  1. 首页
  2. 用水分子作为由电荷辅助键调节的超小极旋转器的晶体超分子陀螺仪
  1. 首页
  2. 用水分子作为由电荷辅助键调节的超小极旋转器的晶体超分子陀螺仪

相关实验视频

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
10:28

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

Published on: May 27, 2018

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用水分子作为由电荷辅助键调节的超小极旋转器的晶体超分子陀螺仪

Wang Li1, Chun-Ting He2, Ying Zeng1

  • 1Key Laboratory of Jiangxi University for Functional Materials Chemistry, College of Chemistry and Chemical Engineering, Gannan Normal University , Ganzhou 341000, China.

Journal of the American Chemical Society
|June 7, 2017

在PubMed 上查看摘要

概括
此摘要是机器生成的。

研究人员开发了一种新型的晶体分子旋转器. 这种超分子陀螺仪具有旋转的水分子,可通过键和相位过渡控制.

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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

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相关实验视频

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
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Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

Published on: May 27, 2018

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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

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科学领域:

  • 超分子化学
  • 材料科学
  • 晶体学

背景情况:

  • 分子机器和旋转器的开发对于纳米技术至关重要.
  • 设计具有可控制动态元件的系统仍然是一个挑战.

研究的目的:

  • 介绍一种用于构建晶体分子旋转器的新策略.
  • 为了研究一种类似于旋转水分子的超分子旋转器.

主要方法:

  • 一个超分子化合物的合成: (t-BuNH3) ((18-皇冠-6) [ZnCl3 ((H2O) ].
  • 用于检测分子旋转的介电松测量.
  • 分析运动的分子动力学模拟.

主要成果:

  • 协调的水分子作为一个超小的极旋转器.
  • 显著的介电放松证实了水分子的旋转.
  • 观察到一个可逆的极点到极点相位过渡.
  • 水分子的旋转可以打开/关闭.

结论:

  • 提出的策略可以构建新的晶体分子旋转器.
  • 超分子陀螺仪展示了水分子的可切换旋转.
  • 控制是通过宿主和键的构造变化实现的.