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Updated: Feb 27, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
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使用化学不稳定的介质剂对有层的金属有机框架进行控制的介质和化学剥离

Yanjun Ding1, Ying-Pin Chen2, Xinlei Zhang1

  • 1Department of Polymer Science and Engineering, CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, China.

Journal of the American Chemical Society
|June 28, 2017
PubMed
概括

研究人员开发了一种创建超薄2D金属有机框架 (MOF) 的新方法. 这种工艺可以产生高质量的MOF纳米板,用于各种应用.

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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