隐藏的海洋? 在地球深处揭开水性缺陷的结构
Helen Grüninger1, Katherine Armstrong1, Dominik Greim1
1Anorganische Chemie III and ‡Bayerisches Geoinstitut, University of Bayreuth , Universitätsstrasse 30, 95447 Bayreuth, Germany.
Journal of the American Chemical Society
|July 8, 2017
概括
高压环木石通过OH缺陷吸收水,形成Mg和Si空隙. 这种缺陷的化学成分对于了解地球的水资源预算和地幔运输特性至关重要.
科学领域:
- 地质化学
- 矿物物理
- 固态化学
背景情况:
- 地球的深层是富含高压酸盐的.
- 这些矿物质可以以基 (OH) 缺陷的形式储存大量的水.
- 水的融入通常涉及空位,如Mg2+.
研究的目的:
- 在水性条件下研究环木 (γ-Mg2SiO4) 的化学缺陷.
- 确定水是如何纳入和电荷平衡在螺旋结构.
- 了解地球水资源预算和地幔属性的影响.
主要方法:
- 高分辨率的多维单量子和双量子1H固态NMR光谱.
- 密度函数理论 (DFT) 的计算.
- 对缺陷结构和收费补偿机制的分析.
主要成果:
- 环木在去除Mg2+的同时形成Si4+空缺,即使含水量低 (0.1%).
- 空位由质子和/或Mg2+和Si4+空位平衡.
- 观察到OH组定向的显著乱和广泛的OH·O债券分布.
结论:
- 对于水性环木石的化学缺陷有了新的见解.
- 解释了地球水资源预算的潜在主要贡献者.
- 缺陷结构影响了类似材料的地幔传输特性和离子导电性.
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