通过三重-三重消灭-基于光子上转变的循环极化发光的放大
Jianlei Han1,2, Pengfei Duan2, Xianggao Li1
1School of Chemical Engineering and Technology, Tianjin University , Tianjin 300072, P. R. China.
Journal of the American Chemical Society
|July 8, 2017
概括
奇拉分子可以通过三倍三倍灭绝光子向上转换 (TTA-UC) 放大循环偏光 (CPL). 这种新的方法显著增强了CPL信号,为奇拉材料设计提供了新的可能性.
科学领域:
- 摄影化学
- 材料科学
- 整形眼镜光谱
背景情况:
- 循环极化发光 (CPL) 对于奇拉识别和感应至关重要.
- 光子上升转换 (UC) 将低能光子转换为高能光子.
- 三倍三倍灭绝 (TTA) 是光子上升转换的一个常见机制.
研究的目的:
- 在TTA-UC系统中证明CPL的放大.
- 研究分子性对UC-CPL的影响.
- 增强CPL的不对称系数 (g_lum).
主要方法:
- 使用了用阿基拉Pt(II) 八甲基胺 (PtOEP) 敏感化的性双甲基胺受体.
- 使用基于溶液的光物理测量.
- 分析了向上转换的循环极化发光 (UC-CPL) 光谱.
主要成果:
- 在TTA-UC系统中首次使用奇拉受体观察到UC-CPL.
- 与受体的R/S性相关的阳性或负性UC-CPL发射.
- 与正常CPL相比,UC-CPL中的g_lum因子增大了一级.
结论:
- 该TTA-UC系统有效地放大了CPL信号.
- 接受者的分子性决定了UC-CPL的手性.
- TTA-UC为设计具有增强不对称因素的CPL材料提供了一种新策略.
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