寻找下一个深紫外线非线性光学材料:NH4B4O6F
Guoqiang Shi1,2, Ying Wang1, Fangfang Zhang1
1Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices , 40-1 South Beijing Road, Urumqi 830011, China.
Journal of the American Chemical Society
|July 21, 2017
概括
研究人员发现NH4B4O6F是一种用于深紫外线激光的新型非线性光学材料. 与KBBF相比,这种材料具有更高的性能和更容易的晶体生长,具有工业应用的潜力.
科学领域:
- 材料科学
- 光学学
- 固态物理
背景情况:
- 非线性光学 (NLO) 材料对于推进固态激光技术至关重要.
- KBe2BO3F2 (KBBF) 是用于深紫外线 (DUV) 连贯光的显著NLO材料,但面临着工业限制.
研究的目的:
- 为DUV应用引入和描述一种新的NLO材料NH4B4O6F.
- 评估其作为KBBF等现有材料的替代品的潜力.
主要方法:
- NH4B4O6F 的结晶和特征.
- 光学属性测量,包括透明度范围和双折.
- 与KBBF进行非线性系数评估和比较.
主要成果:
- NH4B4O6F具有广泛的深紫外透明度范围.
- 它具有适用于低于200nm的频率翻倍的双折射.
- 该材料具有较大的非线性系数,大约是KBBF的2.5倍.
- 大量结晶生长是可行的, 材料中没有有毒元素.
结论:
- NH4B4O6F是一种有前途的新型NLO材料,用于DUV连贯光产生.
- 其增强的非线性特性,易于晶体生长和无毒性使其成为工业应用的强大候选者.
- 这一发现可能会对先进激光系统的发展产生重大影响.
相关概念视频
UV–Vis Spectroscopy: Woodward–Fieser Rules
28.8K
UV–Visible absorption spectra of conjugated dienes arise from the lowest energy π → π* transitions. The light-absorbing part of the molecule is called the chromophore, and the substituents directly attached to the chromophore are called auxochromes. A strong correlation exists between the absorption maxima, λmax, and the structure of a conjugated π system. The Woodward–Fieser rules predict the value of λmax for a given structure by adding the...
28.8K
UV–Vis Spectroscopy of Conjugated Systems
8.6K
Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
One of the factors influencing λmax is the extent of conjugation in...
One of the factors influencing λmax is the extent of conjugation in...
8.6K
Total Internal Reflection Fluorescence Microscopy
13.5K
Total internal reflection fluorescence microscopy or TIRF is an advanced microscopic technique used to visualize fluorophores in samples close to a solid surface with a higher refractive index, such as a glass coverslip. TIRF only allows fluorophores in proximity to the solid surface to be excited. When light from a medium with a lower refractive index (such as air) hits the glass coverslip at a critical angle, the light undergoes total internal reflection stead of passing through the glass.
13.5K


