用喷雾沉积的硫化薄膜的化学成分
Michael J Klein1, Gabriel M Veith2, Arumugam Manthiram1
1Materials Science and Engineering Program and Texas Materials Institute, University of Texas at Austin , Austin, Texas 78712, United States.
Journal of the American Chemical Society
|July 22, 2017
概括
研究人员开发了一种用于先进硫 (Li-S) 电池的硫化物 (Li2S) 膜的新方法. 作为沉积的薄膜显示独特的电化学特性,与化Li2S不同,可实现全容量.
科学领域:
- 材料科学
- 电化学
- 电池技术
背景情况:
- 硫化 (Li2S) 作为高能 (Li-S) 电池的排放产品至关重要.
- 这也是无金属Li-S电池的潜在阴极材料.
研究的目的:
- 制造一种用于喷射Li2S薄膜的装置.
- 为了研究沉积和化Li2S薄膜的结构和电化学特性.
- 了解影响Li2S沉积的等离子体化学反应.
主要方法:
- 控制厚度的Li2S薄膜的喷射沉积.
- 在高温下对Li2S薄膜进行回火.
- 用于化学分析的X射线光电子光谱 (XPS) 和拉曼光谱.
- 电静电充/放电循环用于电化学评估.
主要成果:
- 在速度>2 nm/min时制造Li2S薄膜 (厚度为nm至μm).
- 高温回火产生纯晶的Li2S.
- 喷射沉积形成了一个独特的聚合物状链结构Li2S.
- 与非活跃的化Li2S不同,As沉积薄膜表现出明显的电化学反应,并在充电过程中达到完全的理论容量.
结论:
- 喷沉积的Li2S薄膜具有独特的结构和电化学特性,有利于Li-S电池.
- 这种存储结构可以轻松地进行固态充电.
- 需要进行进一步的研究,以优化血化学和同质的Li2S沉积.
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