识别IROx水分裂催化剂的主要结构特征
Elena Willinger1,2, Cyriac Massué1,2, Robert Schlögl1,2
1Max Planck Institute for Chemical Energy Conversion , Mülheim a.d. Ruhr, Germany.
Journal of the American Chemical Society
|August 11, 2017
概括
研究人员确定了 (水) 氧化物的关键结构特征, 在无形氧化中优化角与边共享的IrO6八面体的比率可以提高的产生.
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- 电催化水分解对于可持续的生产至关重要.
- () 氧化物由于其稳定性和活性,是水氧化的有希望的催化剂.
- 了解无形氧化相的结构-活性关系至关重要但具有挑战性.
研究的目的:
- 识别与高电催化水分裂活动相关的无形氧化水氧的关键结构图案.
- 在X射线无形氧化催化剂中阐明结构-活性关系.
- 引导高活性和稳定的无形氧化催化剂的合理合成.
主要方法:
- 原子对分布函数分析
- 实时空间原子尺度成像
- 当地电子结构测量
主要成果:
- 高电催化活性与角和边缘共享的IrO6八面体的特定比率相关.
- 活性阶段具有类似荷兰石的区域,由低协调的原子相互连接.
- 较不活跃的阶段含有鲁基基基因,导致更快的失活.
结论:
- 八面体的局部排列显著影响了水分裂性能.
- 具有荷兰类域的无形氧化具有优越的活性和稳定性.
- 无形氧化催化剂的合理设计可以通过控制结构图案来实现.
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