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相关概念视频

Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.0K
Valence Bond Theory02:42

Valence Bond Theory

11.4K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.4K
Colors and Magnetism03:02

Colors and Magnetism

14.2K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
14.2K
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

1.8K
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
1.8K
Bonding in Metals02:32

Bonding in Metals

53.9K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
53.9K
Coordination Number and Geometry02:57

Coordination Number and Geometry

19.2K
For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
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相关实验视频

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Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
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金属-有机框架中的金属行为特征 M3() 2 (M = Ni,Cu)

Jin-Hu Dou1, Lei Sun1, Yicong Ge1

  • 1Department of Chemistry, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|September 15, 2017
PubMed
概括

研究人员在新的金属有机框架 (MOF) 中发现了金属行为. 这些材料Ni3 ((HIB) 2和Cu3 ((HIB) 2具有电导性,并保持其多孔结构,这是材料科学的重大进步.

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科学领域:

  • 材料科学
  • 固态化学
  • 纳米技术

背景情况:

  • 金属有机框架 (MOF) 通常是绝缘体或半导体.
  • 在保持多孔性的同时,在MOF中实现电导率是一个重大挑战.

研究的目的:

  • 研究二维连接的MOF的电性,特别是Ni3 ((HIB) 2) 和Cu3 ((HIB) 2).
  • 确定MOF中的金属行为是否可以与永久性多孔性共存.

主要方法:

  • 合成和表征Ni3 ((HIB) 2) 和Cu3 ((HIB) 2) MOF.
  • 大量电导度测量.
  • 紫外光电子光谱 (UPS).
  • 电子带结构计算.
  • 结构特征和显微镜.

主要成果:

  • Ni3 ((HIB) 2) 和Cu3 ((HIB) 2) 具有大量的电导性.
  • 无线电系统的信号与金属固体相一致.
  • 电子带结构计算显示费米能量位于一个部分填充的移位带中.
  • 这些MOF表明金属行为和永久性多孔性的共存.

结论:

  • 这项研究报告了金属行为在多孔金属有机框架的第一例.
  • Ni3 ((HIB) 2) 和Cu3 ((HIB) 2) 是一种新的导电性多孔材料.
  • 这些发现为MOF在电子和催化应用开辟了道路.