寡合离子液体的异常高电双层容量
Michio Matsumoto1, Sunao Shimizu2, Rina Sotoike3
1Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Journal of the American Chemical Society
|October 12, 2017
概括
一种新型的寡合离子液体,IL4TFSI,显著提高了电双层电容器的性能. 这种材料具有高容量和广的电化学窗口,进步了储能技术.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 电双层电容器 (EDL) 需要高容量和高工作电压来储存下一代的能量.
- 很少有电解质可以同时满足这些要求.
研究的目的:
- 作为EDL电容器的先进电解质,研究一种寡合离子液体IL4的潜力.
- 与单体离子液相比,评估其电化学窗口和EDL电容.
主要方法:
- 使用电化学阻抗光谱测量EDL电容用金 (Au) 工作电极.
- 霍尔效应测量用于确定场效应晶体管 (FET) 设置中的载体积累能力.
主要成果:
- IL4TFSI显示了大约5.0V的宽电化学窗口.
- 达到了约66μF/cm2的异常高EDL电容,大约是单体离子液体的6倍.
- 使用IL4的基于EDL的FET显示了大约64μF/cm2的增强载体积累.
结论:
- 像IL4TFSI这样的寡合离子液体为高性能EDL电容提供了有前途的途径.
- IL4TFSI显著提高容量和载体积累,优于传统的单体离子液体.
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