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相关概念视频

Electromotive Force02:36

Electromotive Force

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Electricity is generated by either electrons or ions flowing through a solution or a conducting medium. This flow of electrons or specifically electrical charge is defined as an electric current. When electrons move through a wire, they generate an electric current. It can be recalled  that in a redox reaction, electrons are lost and gained. In the spontaneous redox reaction of zinc  with copper, when zinc is immersed in a copper ion solution, a transfer of electrons from one substance to...
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Electromotive Force01:02

Electromotive Force

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Electromotive force (emf) is the force that causes current to flow from a higher to a lower  potential. The term "electromotive force" is used for historical reasons, even though emf is not a force at all.
Any circuit with a constant current must contain an emf-producing source. Examples of emf sources include batteries, electric generators, solar cells, thermocouples, and fuel cells. All these sources transform energy of some kind (mechanical, chemical, thermal, and so on)...
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Thomson's e/m Experiment01:19

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In a beam of charged particles created by a heated cathode, the particles move at different speeds. However, many applications need a beam with uniform particle speeds. An arrangement known as a velocity selector uses electric and magnetic fields to pick particles with a particular speed from the beam.
A particle with charge q, speed v, and mass m enters an area from the top, where the magnetic and electric fields are perpendicular both to the particle's motion and to one another. The magnetic...
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Carrier Generation and Recombination01:22

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Carrier generation is the process by which electron-hole pairs (EHPs) are created within the semiconductor. In direct-bandgap semiconductors, such as gallium arsenide (GaAs), this occurs efficiently when energy absorption prompts valence electrons to leap into the conduction band, leaving behind holes.
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
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Electrochemical Systems01:24

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Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution,...
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The Electrical Double Layer01:30

The Electrical Double Layer

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In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
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在电子传输链中调节电荷转移反应

Maximilian Wolf1, Carmen Villegas2, Olga Trukhina3,4

  • 1Department of Chemistry and Pharmacy & Interdisciplinary Center of Molecular Materials (ICMM), Friedrich-Alexander-University Erlangen-Nuremberg , Egerlandstr. 3, 91058 Erlangen, Germany.

Journal of the American Chemical Society
|October 14, 2017
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概括

研究人员为高效的电荷传输合成了新型的电子供体-接受体结合物. 这种策略利用与烯对相连的氨酸或氨酸来实现单向,远程的电荷转移,最大限度地减少能量损失.

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科学领域:

  • 材料科学
  • 摄影化学
  • 超分子化学

背景情况:

  • 共价供体-接受体结合物对于人工光合作用和分子电子学至关重要.
  • 有效的电荷传输需要在电子传输过程中最大限度地减少能量损失.

研究的目的:

  • 合成和描述一种新的捐赠者-接受者1-接受者2联物.
  • 研究这些系统中的电荷转移动态和能量转移机制.

主要方法:

  • 合成基于二和二的合物.
  • 用于激发状态动态的五秒暂时吸收光谱.
  • 暂时吸收光谱的计算分析.

主要成果:

  • 从激发的供体到富勒伦对 (C60和C70) 的单向,远程电荷传输证明.
  • 确定了短距离电荷转移过程的级联,包括还原性电荷转移.
  • 对电荷转移动学的间隔器组的观察影响.

结论:

  • 开发的策略有效地建立了一个微调的氧化还原梯度,以实现高效的电荷传输.
  • 建议在弱电子合下进行电荷转移反应.
  • 在三倍三倍的能量转移和电荷转移之间有着密切的关系.