动态同位素效应为甲基三化矿中质子道化提供实验证据
Yan-Fang Chen1,2, Yu-Tang Tsai1,2, Lionel Hirsch1,2
1Université Bordeaux, CNRS, UMR 5218, IMS , F-33400 Talence, France.
Journal of the American Chemical Society
|October 26, 2017
概括
通过同位素标记证实了混合矿中的质子道. 化揭示了这些材料中的质子迁移机制和能量障碍.
科学领域:
- 材料科学
- 固态物理
- 化学物理
背景情况:
- 像MAPbI3这样的混合有机-无机矿是各种电子应用的有希望的材料.
- 了解离子迁移机制对于设备的稳定性和性能至关重要.
- 甲基 (MA) 组件中的质子迁移可以影响材料特性.
研究的目的:
- 研究MAPbI3矿中质子道的发生和机制.
- 阐明同位素替代在质子迁移动态上的作用.
- 确定不同矿阶段与质子迁移相关的激活能量.
主要方法:
- 用标记甲基 (MA) 组件的同位素.
- 测量介电性响应.
- 主要和次要动态同位素效应的分析.
- 激活能量和预指数因子的计算.
主要成果:
- 氨基基组的化加速了质子迁移 (反向原始同位素效应).
- 甲基的化显示出正常的二次同位素效应.
- 质子迁移的激活能量为50 meV (四边形) 和27 meV (正方形),随着二化而下降.
- 低激活屏障和A_H/A_D比率 (0.3-0.4) 表示质子道.
结论:
- 质子道是MAPbI3矿中质子迁移的一个重要机制.
- 同位素标记提供了一个强大的工具来区分道与其他迁移机制.
- 来自PEDOT:PSS层的外部离子迁移可以影响观察到的矿的行为.
更多相关视频
09:00Electrochemical Detection of Deuterium Kinetic Isotope Effect on Extracellular Electron Transport in Shewanella oneidensis MR-1
Published on: April 16, 2018
10.7K
08:12Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films
Published on: September 8, 2017
10.1K
相关概念视频
Isotopes
64.6K
Elements have a set number of protons that determines their atomic number (Z). For example, all atoms with eight protons are oxygen; however, the number of neutrons can vary for atoms of the same element. The sum of the number of protons and the number of neutrons is the mass number (A). Atoms with the same atomic number but different mass numbers are called isotopes. Elements can have multiple isotopes, for example, carbon-12, carbon-13, and carbon-14.
An element's atomic mass, or weight,...
An element's atomic mass, or weight,...
64.6K
Elements: Chemical Symbols and Isotopes
126.3K
A chemical symbol is an abbreviation used to indicate an element or an atom of an element. For example, the symbol for mercury is Hg. The same symbol is used to indicate one atom of mercury (microscopic domain) or to label a container of many atoms of the element mercury (macroscopic domain).
Some symbols are derived from the common English name of the element; others are abbreviations of the name in another language — Latin, Greek or German. For example, the symbol for aluminum (common name)...
Some symbols are derived from the common English name of the element; others are abbreviations of the name in another language — Latin, Greek or German. For example, the symbol for aluminum (common name)...
126.3K
The Evidence for Evolution
48.3K
Genetic variations accumulating within populations over generations give rise to biological evolution. Evolutionary changes can result in the formation of novel varieties and entire new species. These changes are responsible for the diverse forms of life inhabiting the planet. The evidence for evolution suggests that all living organisms descended from common ancestors.
48.3K
Kinetic Energy
43.4K
Kinetic energy is the ability of an object in motion to do work or enact change. It can take on many forms. For instance, water flowing down a waterfall has kinetic energy. In biological systems, particles of light travel and are absorbed by plants to create chemical energy. Animals consume the chemical energy and give off molecules that carry their scent through the air. They also generate kinetic energy when they run away from predators. Entire systems also possess kinetic energy, like the...
43.4K
Enzyme Kinetics
104.1K
Enzymes speed up reactions by lowering the activation energy of the reactants. The speed at which the enzyme turns reactants into products is called the rate of reaction. Several factors impact the rate of reaction, including the number of available reactants. Enzyme kinetics is the study of how an enzyme changes the rate of a reaction.
Scientists typically study enzyme kinetics with a fixed amount of enzyme in the controlled environment of a test tube. When more reactant, or substrate, is...
Scientists typically study enzyme kinetics with a fixed amount of enzyme in the controlled environment of a test tube. When more reactant, or substrate, is...
104.1K
Kinetic Molecular Theory: Molecular Velocities, Temperature, and Kinetic Energy
29.9K
The kinetic molecular theory qualitatively explains the behaviors described by the various gas laws. The postulates of this theory may be applied in a more quantitative fashion to derive these individual laws.
29.9K
