无分子铁电薄膜中的大型压电效应
Wei-Qiang Liao1, Yuan-Yuan Tang1, Peng-Fei Li1
1State Key Laboratory of Bioelectronics, and Ordered Matter Science Research Center, Southeast University , Nanjing 211189, P. R. China.
Journal of the American Chemical Society
|November 17, 2017
概括
一种新的无分子铁电,三甲基甲三甲 (TMBM-MnBr3),具有112 pC/N的显著压电系数 (d33). 这一发现为开发下一代压电器提供了有希望的替代方案.
科学领域:
- 材料科学
- 固态物理
- 铁电行业
背景情况:
- 酸陶 (PZT) 占据了压电市场的主导地位,但含有有毒.
- 需要具有可比性能的无压电材料.
- 分子铁电具有灵活性和环保处理等优势.
研究的目的:
- 报告一个新的无,单组合分子铁电材料.
- 描述其压电和铁电性质.
- 评估其下一代压电器的潜力.
主要方法:
- 三甲基甲三甲 (TMBM-MnBr3) 的合成和表征
- 在极轴上测量压电系数 (d33).
- 评估铁电性能,包括强制电压和多轴特性.
- 薄膜和散装晶体的压电性能比较
主要成果:
- TMBM-MnBr3具有112 pC/N的大压电系数d33,相当于PZT,优于大多数分子铁电.
- TMBM-MnBr3薄膜的有效局部压电系数与其散体晶体相似.
- 低强制电压和多轴特性促进了压膜的应用.
结论:
- TMBM-MnBr3是一种有前途的无分子铁电,具有出色的压电特性.
- 它的薄膜性能和处理优势为工业和医疗压电设备开辟了新的途径.
- 这种材料为基压电材料提供了可持续的替代品.
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