高性能双极晶体管的区域常规双[2,1,3]亚二醇基半导体聚合物
Chunguang Zhu1, Zhiyuan Zhao2, Huajie Chen1
1Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University , Xiangtan 411105, People's Republic of China.
Journal of the American Chemical Society
|November 22, 2017
概括
研究人员使用bis-pyridal[2,1,3]-thiadiazole (BPT) 单元开发了一种新的半导体聚合物. 这种聚合物表现出极好的双极电荷传输,显示出高性能有机电子的前景.
科学领域:
- 有机电子产品
- 材料科学
- 聚合物化学
背景情况:
- 开发高性能有机半导体对于电子设备的发展至关重要.
- 两极聚合物既能携带孔,也能携带电子,
研究的目的:
- 合成和描述基于pyridal[2,1,3]thiadiazole单元的第一个双极半导体聚合物.
- 调查 bis-pyridal[2,1,3]-thiadiazole (BPT) 接受器单元对聚合物特性和电荷传输的影响.
主要方法:
- 合成包含BPT单元的半导体聚合物.
- 聚合物的电子特性,包括能量水平和π-结合.
- 测量孔和电子的移动性
主要成果:
- 首个基于二极性化[2,1,3]半导体聚合物 (PBPTV) 的成功合成.
- 由于BPT单元,PBPTV具有较高的电子亲和度和较低的LUMO水平.
- 获得的孔和电子流动性分别为6.87厘米V1和8.49厘米V2.
结论:
- BPT装置是制造高性能双极有机半导体的有效策略.
- PBPTV在有机电子领域的应用潜力显著,特别是电子传输材料.
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