分子黄金集群的聚合诱导光转光转换
Mizuho Sugiuchi1, Junichi Maeba2, Nobuyuki Okubo2
1Graduate School of Environmental Science, Hokkaido University , North 10 West 5, Sapporo 060-0810, Japan.
Journal of the American Chemical Society
|November 28, 2017
概括
聚合极大地改变了黄金集群的光学特性. 单体会发出光,而聚合物则表现出增强的光,为新材料设计开辟了道路.
科学领域:
- 材料科学
- 纳米技术
- 摄影化学
背景情况:
- 聚合诱导的排放是各种化合物的已知现象.
- 黄金集群表现出独特的光学特性,
研究的目的:
- 调查聚合对[核心+外]型[Au8]4+星团的光发光 (PL) 的影响.
- 了解聚合时发射模式从光到光的转变.
主要方法:
- [Au8]4+集群的合成和特征.
- 溶剂依赖光发光谱学
- 生命周期测量以区分光和光.
- 激发光谱用于研究集群组件.
主要成果:
- 在可溶性溶剂中的单体[Au8]4+集群在~600nm时呈现光.
- 聚合会诱导一个新的光发射带在700nm.
- 固态光表现出比单体光高两倍的量子效率.
结论:
- 集群聚合极大地影响光学特性,使其从光转变为光.
- 有组织的集群组件负责增强,低能量的光.
- 这种聚合效应为设计基于集群的高级功能材料提供了潜力.
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