离子混合电解质-超级电容系统的选择性充电行为,以获得更高的能量和功率
Xuehang Wang1,2, Aleksandar Yordanov Mehandzhiyski1, Bjørnar Arstad3
1Department of Chemical Engineering, Norwegian University of Science and Technology , 7491 Trondheim, Norway.
Journal of the American Chemical Society
|November 30, 2017
概括
这项研究通过使用混合离子电解质来提高超级电容器 (SC) 的性能. 不同的离子相互作用使先进的SC系统能够同时增加功率和能量密度.
科学领域:
- 电化学
- 材料科学
- 物理化学
背景情况:
- 离子-离子相互作用极大地影响超级电容器 (SC) 的性能.
- 削弱这些相互作用会增加SC的能量,但会降低能量密度.
- 优化SC需要平衡功率和能量密度.
研究的目的:
- 实现电力和能源密度的同时提升.
- 研究具有不同离子相互作用的混合离子电解质的影响.
- 在封闭的多孔结构中探索选择性离子充电.
主要方法:
- 使用具有明显阴离子相互作用的离子混合电解质.
- 使用固态核磁共振 (NMR) 实验.
- 使用密度函数理论 (DFT) 和分子动力学 (MD) 模拟进行理论验证.
主要成果:
- 证实了SC功率和能量密度的同时提升.
- 展示了选择性的离子包装:在中孔中相互作用的阴离子较强,在微孔中较弱.
- 证实微孔中较弱的相互作用保持功率密度.
结论:
- 离子混合电解质与封闭的多孔材料相结合,为SC增强提供了一种新方法.
- 不同孔径的选择性离子充电是优化SC性能的关键.
- 这一战略为超级电容系统的全面改进提供了途径.
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