单片裂变涉及烯二胺膜中的能量驱动力和电子合之间的相互作用
Aaron K Le1, Jon A Bender1, Dylan H Arias2
1Department of Chemistry, The University of Texas at Austin , Austin, Texas 78712-1224, United States.
Journal of the American Chemical Society
|December 15, 2017
概括
在perylenediimide膜中单片裂变通过控制分子包装产生178%的三片激子. 有效的光稳定材料需要优化激子的产生和提取.
科学领域:
- 有机半导体光物理
- 用于能源应用的材料科学
背景情况:
- 单片裂变弥补了光收获中的热化损失.
- 开发用于定量单片裂变的光稳材料具有挑战性.
研究的目的:
- 在perylenediimide膜中通过单片裂变探索三重激素的产生.
- 研究分子包装对单片裂变效率的影响.
主要方法:
- 合成了具有多种功能组的列二胺衍生物.
- 制造的薄膜和受控的分子包装.
- 使用短暂吸收光谱测量三重激子产量和裂变速率.
主要成果:
- 实现了178%的最大三产量,裂变速率为~245 psi.
- 最佳的包装需要在perylenediimides之间进行~3 Å的长轴位移.
- 在几十纳秒内观察到三重激子衰变.
结论:
- 分子包装在perylenediimides中显著影响单片裂变效率.
- 单片裂变材料需要设计用于激子的产生和提取.
- 结果与雷德菲尔德理论一致, 表明电荷转移中介的超级交换机制.
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