可逆激光诱导曲的伪毒素晶体
Shao-Chi Cheng1, Kai-Jen Chen1, Yuji Suzaki2
1Department of Chemical Engineering, National Tsing Hua University , 101, Sec. 2, Kuang-Fu Road, Hsinchu 30013, Taiwan.
Journal of the American Chemical Society
|December 26, 2017
概括
这项研究揭示了含有阿佐基的伪晶体在光照射时呈现出快速可逆的曲. 这种光响应可以通过分子结构调整,为光激活材料提供潜力.
科学领域:
- 超分子化学
- 材料科学
- 摄影化学
背景情况:
- 伪素是超分子组件,在分子机器中具有潜在的应用.
- 亚和铁基是已知的光响应部分.
研究的目的:
- 研究含有亚博和铁单元的伪晶体的动态光反应.
- 将分子结构与观察到的光诱导曲行为相关联.
主要方法:
- 使用X射线结晶学来确定伪晶体的结构特征.
- 使用特定波长 (360 nm 和 445 nm) 的交替激光照射来诱导和观察光反应.
主要成果:
- 有甲基基的伪晶体显示出显著的扭曲 (17°和38°).
- 经过多次照射,可以在20-30°的方向上进行可逆曲,而不会发生衰变.
- 由于强烈的π-π相互作用,非被替代的伪素呈现最小的曲 (2°).
结论:
- 伪晶体具有可调节,快速和可逆的光响应曲能力.
- 分子结构,包括亚博替代剂和π-π相互作用,决定了光诱导曲的效率和方向.
更多相关视频
相关概念视频
Bending
939
Pure bending is a fundamental concept in structural mechanics, essential for understanding how materials deform under symmetrical loads without direct forces. Pure bending occurs when prismatic members, such as beams, are subjected to equal and opposite moments that induce bending. The phenomenon is crucial as it allows for predicting stress distributions without the influence of axial or shear forces.
In pure bending, the bending stress in a beam is calculated based on the bending moment and...
In pure bending, the bending stress in a beam is calculated based on the bending moment and...
939
Ionic Crystal Structures
18.1K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
18.1K
Symmetric Member in Bending
623
In the study of the mechanics of materials, analyzing the behavior of prismatic members under opposing couples is crucial for understanding internal stress distributions, which are essential for structural design. When subjected to couples, a prismatic member experiences internal forces that maintain equilibrium. A couple, characterized by two equal and opposite forces, creates a moment but no resultant force. The internal forces at any section cut of the member must balance these external...
623
Unsymmetric Bending
856
Unsymmetrical bending occurs when the bending moment applied to a structural member does not align with its principal axis. This misalignment leads to complex stress distributions and deflection patterns that differ from those in symmetrical bending, and are essential for designing structures to withstand different loading conditions. In unsymmetrical bending, the neutral axis—where stress is zero—does not necessarily align with the geometric axes of the cross-section. The...
856
Crystal Growth: Principles of Crystallization
5.2K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
5.2K
Bending of Members Made of Several Materials
629
In analyzing a structural member composed of two different materials with identical cross-sectional areas, it is crucial to understand how their distinct elastic properties affect the member's response under load. The analysis involves assessing stress and strain distributions using the transformed section concept, which accounts for variations in material properties.
Hooke's Law determines stress in each material, stating that stress is proportional to strain but varies due to each material's...
Hooke's Law determines stress in each material, stating that stress is proportional to strain but varies due to each material's...
629


