在磁性和金属Tb ((Co,Fe) 2金属间化合物中零热膨胀
Yuzhu Song1, Jun Chen1, Xinzhi Liu2
1Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
Journal of the American Chemical Society
|January 3, 2018
概括
研究人员在磁性Tb (Co,Fe) 2金属间化合物中发现了零热膨胀 (ZTE). 这种罕见的金属材料在广泛的温度范围内呈现微不足道的热膨胀,使其成为先进应用的前景.
科学领域:
- 材料科学
- 凝聚物质物理学
- 磁力学
背景情况:
- 零热膨胀 (ZTE) 材料在需要在温度变化中保持尺寸稳定性的应用中非常受欢迎.
- 基于金属的ZTE化合物特别罕见,在材料开发中构成重大挑战.
- 对于设计ZTE新型材料来说,了解磁顺序和格子动态之间的相互作用至关重要.
研究的目的:
- 在一个新的磁性金属间化合物中发现零热膨胀 (ZTE).
- 在Tb(Co,Fe) 2中研究ZTE的温度范围和特征.
- 阐明对观察到的ZTE属性的潜在物理机制.
主要方法:
- 合成和表征Tb (Co,Fe) 2金属间化合物.
- 在广泛的温度范围 (123-307 K) 上使用扩展计测量热膨胀系数.
- 磁性测量和结构分析以了解铁磁排序和磁阻力效应.
主要成果:
- 在Tb(Co,Fe) 2中观察零热膨胀 (ZTE),在Tb(Co1中忽略不计的热膨胀系数 (αl = 0.48 × 10-6 K-1).
- 这些化合物具有铁磁结构,Tb和Co/Fe磁矩沿c轴对齐.
- ZTE是由负自发磁缩 (从Tb时刻开始) 和正格子扩张之间的平衡引起的.
结论:
- Tb(Co,Fe) 2化合物在异常广泛的温度范围内表现出一种罕见的基于金属的零热膨胀 (ZTE) 特性.
- 这种ZTE行为归因于磁性排序和晶格动态的独特相互作用.
- 这些材料具有应用潜力,因为它们具有维度稳定性,高电和热导率.
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