超原子银纳米集群的原子精确定制和定向组装
Zhao-Yang Wang1, Meng-Qi Wang1, Yan-Ling Li1
1College of Chemistry and Molecular Engineering, Zhengzhou University , Zhengzhou 450001, China.
Journal of the American Chemical Society
|January 4, 2018
概括
研究人员使用新型配体开发了稳定的超原子银团 (Ag14). 这些集群可以精确地组装成具有可调的双排放和热色的先进材料,提高稳定性和功能.
科学领域:
- 材料科学
- 纳米技术
- 无机化学
背景情况:
- 制造稳定的超原子银团和控制它们的组合是一个重大挑战.
- 现有的方法往往缺乏对特定地点的定制和定向组装的控制.
- 超原子集群具有独特的特性,但需要强大的联体保护以保持稳定性.
研究的目的:
- 开发一种便于生成稳定的超原子银 (Ag14) 的方法.
- 实现这些集群的特定地点定制和定向组装成先进的材料.
- 研究连体对集群稳定性,组装和光学特性的影响.
主要方法:
- 面中心立方 (fcc) Ag14超原子的制备,由1,2-dithiolate-o-carborane连接物保护.
- 在结晶过程中同时将Ag+减少为Ag0.
- 使用基体和桥接体进行组装的特定位点的体交换.
- 集群稳定性,结构和光学特性 (发光,热色) 的表征.
主要成果:
- 通过dithiolate-o-carborane和pyridine连接物成功合成了超稳定的Ag14超原子 (在空气中高达150°C).
- 构建有层次的1D至3D超原子集群材料 (SCAM),具有增强的空气稳定性 (SCAM-4最高可达220°C).
- 在组装材料中观察到可调的双发射和广泛的热色.
- 在增强稳定性和发光方面证明了角N-捐赠体的主要作用.
结论:
- 这项研究在超原子银纳米集群的控制合成和组装方面取得了重大进展.
- 这些材料的稳定性,结构控制和功能性都很强大.
- 开发的超原子银集成材料具有先进应用的有前途性质.
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