快速离子导电的化共价有机框架纳米板
Hongwei Chen1, Hangyu Tu1, Chenji Hu2
1College of Materials Science and Engineering, Huaqiao University , Xiamen 361021, People's Republic of China.
Journal of the American Chemical Society
|January 6, 2018
概括
通过分裂离子对来提高离子导电性. 这一突破为电池中先进的固态电解质提供了有前途的途径.
科学领域:
- 材料科学
- 电化学
- 固态离子体
背景情况:
- 由于其多孔结构,共价有机框架 (COF) 被探索为离子电池的固态电解质.
- 在COF中透的盐通常会形成离子对,阻碍有效的离子 (Li+) 导电.
- 开发能使这些离子对分离的策略对于改善离子导电性至关重要.
研究的目的:
- 增强固态离子导体应用中COF的离子导电性.
- 为了解决COF孔内的Li+盐离子配对造成的缓慢离子扩散的限制.
- 研究将阴离子骨架纳入COF以改善Li+运输的效果.
主要方法:
- 具有集成的阴离子骨架的COF的设计和合成
- 将Li+盐纳入修改后的COF结构
- 测量Li+导电性的电化学特征.
- 对离子对解离和介电选效应的分析.
主要成果:
- 阴离子骨架有效选Li+盐离子对,增加自由Li+离子度.
- 在70°C达到2.09 × 10^-4 S cm^-1的显著提高的Li+导电性.
- 在没有任何液体溶剂的情况下证明了高离子导电性.
结论:
- 将阴离子骨架纳入COF是一种有效的策略,以提高固态电解质中的Li+导电性.
- 开发的COF材料显示出在先进的固态离子电池中使用的潜力.
- 这种方法克服了传统COF电解质的离子配对的局限性.
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