在酸稳定电池的表面化学
Yiren Zhong1,2, Lichang Yin3, Peng He1,2
1Department of Chemistry, Yale University , New Haven, Connecticut 06520, United States.
Journal of the American Chemical Society
|January 9, 2018
概括
像CoP这样的过渡金属化合物的表面氧化层能够强烈地结合聚硫化物. 这种机制提高了电池中的硫阴极的稳定性和性能.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 硫电池的稳定循环需要限制聚硫化物中间体.
- 了解控制聚硫化物的化学相互作用至关重要,但有限.
研究的目的:
- 报告一种新的,一般的聚硫化物结合机制.
- 研究表面氧化层在过渡金属化物和化物中的作用.
主要方法:
- CoP纳米粒子及其氧化产物的特征.
- 对COP表面的多硫化物吸附的研究.
- 用CoP修改的硫阴极对硫电池进行电化学测试.
主要成果:
- 由于表面氧化形成Co-O-P物种,CoP纳米颗粒表现出强烈的聚硫化物吸附.
- 激活的表面Co位点与多硫化物形成强大的Co-S键.
- CoP纳米粒子提供稳定的硫阴极,具有高质量负载 (7 mg cm−2) 和面积容量 (5.6 mAh cm−2),循环200次.
结论:
- 表面氧化诱导的聚硫化结合是一种适用于各种过渡金属化合物的一般机制.
- 这种机制增强了聚硫化物封闭和电化学转换,稳定了硫阴极.
- CoP纳米粒子有望提高硫电池的性能.
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