Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

31.0K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
31.0K
Bonding in Metals02:32

Bonding in Metals

53.0K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
53.0K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

48.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
48.7K
Metallic Solids02:37

Metallic Solids

21.0K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.0K
Ionic Crystal Structures02:42

Ionic Crystal Structures

18.1K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
18.1K
Alkali Metals03:06

Alkali Metals

25.0K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
25.0K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Optically Detected Magnetic Resonance of a Cerium-Doped Nanocrystal: Toward the Generality of a Direct Spin-Optical Interface.

Journal of the American Chemical Society·2026
Same author

Heteronuclear MOF Heterostructures Based on Identical Auxiliary-Ligand Bridging for Multi-Function-Integrated Photonic Devices.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

One-Pot CO<sub>2</sub> Hydrogenation Coupled With In Situ Esterification for Polyester Monomers Production Over Single-Atom Cu<sup>δ+</sup>-Doped 1.8 Nm T-ZrO<sub>2</sub>.

Angewandte Chemie (International ed. in English)·2026
Same author

Cascade Oxidation of Ethylene and Propylene over a Redox Heterometallic Cluster.

Journal of the American Chemical Society·2026
Same author

Ordered Hollow Sphere Array Nanoreactors for Direct Electroreduction of Diluted CO<sub>2</sub> Into Ethylene.

Angewandte Chemie (International ed. in English)·2026
Same author

Novel Carborane Based Metal Organic Framework for Record Electronic Specialty Gas C<sub>2</sub>F<sub>6</sub> Purification via Molecular Sieving.

Angewandte Chemie (International ed. in English)·2026

相关实验视频

Updated: Feb 15, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.3K

有序的宏微孔金属有机框架单晶

Kui Shen1, Lei Zhang1, Xiaodong Chen1

  • 1School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.

Science (New York, N.Y.)
|January 13, 2018
PubMed
概括
此摘要是机器生成的。

研究人员创建了新型单晶金属有机框架 (MOF),具有有序的宏观和微孔. 这些层次的MOF表现出增强的质量扩散,导致体积较大的分子的超级催化.

更多相关视频

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
05:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

3.9K
Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
07:45

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

Published on: August 16, 2018

10.5K

相关实验视频

Last Updated: Feb 15, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.3K
Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
05:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

3.9K
Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
07:45

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

Published on: August 16, 2018

10.5K

科学领域:

  • 材料科学
  • 纳米技术
  • 化学工程

背景情况:

  • 传统的金属有机框架 (MOF) 往往缺乏层次的孔隙结构,限制了它们在涉及大型分子的反应中的效率.
  • 在单晶MOF中实现有序的宏和微性一直是材料科学中的一个重大挑战.

研究的目的:

  • 开发一种在MOF单晶中构建高度定向和有序的宏孔的方法.
  • 在单晶形式创建一个新的三维排序的宏微孔质材料.
  • 调查这些新型分层MOF对大分子反应的催化性能.

主要方法:

  • 使用聚烯纳米圈单体模板来诱导强烈的塑造效果.
  • 采用双溶剂诱导的异质核化方法来控制MOF生长.
  • 在有序的空隙中实现MOFs的现场生长,以形成具有层次性多孔性的单晶.

主要成果:

  • 在MOF单晶中成功构建高度定向和有序的宏孔.
  • 证明了具有宏观和微孔的单晶材料的形成 (层次性多孔性).
  • 与传统的ZIF-8相比,在层次的MOF中观察到显著改善的质量扩散特性.

结论:

  • 开发的方法允许合成独特的单晶宏微孔性MOF.
  • 层次的孔隙结构和单晶性质导致了较高的催化活性和大分子反应的可回收性.
  • 这项工作为催化和其他应用设计先进的多孔材料开辟了新的途径.