使用X射线相成像在电池操作期间离子电解质盐度分布的定量可视化
Daiko Takamatsu1, Akio Yoneyama1, Yusuke Asari1
1Research & Development Group, Hitachi, Ltd. , Hitachi-shi, Ibaraki 319-1292, Japan.
Journal of the American Chemical Society
|January 17, 2018
概括
在运行过程中可视化离子电池电解质中的盐度至关重要. 操作式X射线相位成像提供了一种多功能方法来定量地绘制这些分布并确定盐的扩散率.
科学领域:
- 材料科学
- 电化学
- 化学工程
背景情况:
- 最佳的离子电池性能取决于了解电解质盐的度.
- 目前在电池运行期间量化盐分发的技术是有限的.
研究的目的:
- 展示在操作中的X射线相位成像对于电解质盐度分布的定量可视化的能力.
- 为了确定不同初始盐度的电解质中的盐扩散率.
主要方法:
- 用于操作式X射线相位成像,观察电池电解质的动态变化.
- 在稳定状态下进行盐度分布的定量分析.
主要成果:
- 在电池运行期间成功可视化了实时的定量盐度分布.
- 获得不同初始盐度的电解质的盐扩散度.
结论:
- 在操作过程中,X射线相位成像是评估各种电化学系统中的电解质行为的一种强大而通用的技术.
- 这种方法提供高空间和时间分辨率,无样本限制,适用于水性和非水性电解质.
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