提高金属化物超四面体纳米团的尺寸限制
Xiaofan Xu1, Wei Wang1, Dongliang Liu1
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University , Suzhou, Jiangsu 215123, China.
Journal of the American Chemical Society
|January 17, 2018
概括
研究人员合成了迄今为止最大的超四面体集群 (T6),推进了对硫化 (ZnS) 纳米粒子的研究. 这一突破使我们对基于集群的 (Mn) 排放产生了新的见解.
科学领域:
- 材料科学
- 纳米技术
- 无机化学
背景情况:
- 立方硫化 (ZnS) 结构对于纳米粒子特性至关重要.
- 合成这种类型的大型精确原子集群,特别是超出已知的T5大小,一直是一个重大挑战.
- 之前的研究只发现了较小的超四面体星团 (T2-T5).
研究的目的:
- 报告ZnS结构类型最大的超四面体集群 (T6).
- 研究这些新星团作为光学活跃中心的主机的潜力.
- 探索 (Mn) 的化及其对排放特性的影响.
主要方法:
- 新型超四面体群的合成.
- 将 (Mn) 剂纳入T4和T6集群.
- 用Mn-doped集群进行表征,以研究排放特性.
主要成果:
- 成功合成了迄今为止最大的超四面体星团T6 ([Zn25In31S84]25-).
- 开发了T4和T6集群的Mn-doped变体.
- 阐明了Mn发射的机制,将其与尺寸依赖的晶格应变联系起来.
结论:
- T6集群代表了集群合成的重大进步.
- 在光学应用上提供了新的可能性.
- 这项研究提供了对基于集群的素的Mn-doping化学的原子层次见解.
相关概念视频
Metallic Solids
21.0K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.0K
Limiting Reactant
70.7K
The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in reality, the reactants are not always present in the stoichiometric amounts indicated by the balanced equation.
70.7K
Bonding in Metals
53.0K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
53.0K
Properties of Transition Metals
30.1K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
30.1K
Alkali Metals
25.0K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
25.0K
The Number e as a Limit
104
The number e is a fundamental constant in calculus, playing a central role in describing continuous change, particularly exponential growth. It is most naturally defined through its relationship with the natural logarithm, which is the inverse of the exponential function with base e. This relationship allows e to be characterized using basic principles of differentiation rather than as an arbitrary numerical constant.A key property of the natural logarithm function, ln x, is that its derivative...
104


