Ce3+-用于调节光发射动力学,用于高效的基于纳米晶体的发光二极管
Ji-Song Yao, Jing Ge, Bo-Ning Han1
1MIIT Key Laboratory of Advanced Display Materials and Devices, Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering , Nanjing University of Science and Technology , Nanjing 210094 , China.
Journal of the American Chemical Society
|January 18, 2018
概括
用Ce3+离子合无机矿CsPbBr3纳米晶体显著提高它们的发光特性. 这种增强导致更明亮,更高效的发光二极管 (LED).
科学领域:
- 材料科学
- 纳米技术
- 固态物理
背景情况:
- 无机矿CsPbBr3纳米晶体 (NCs) 由于高颜色纯度和热稳定性,可以作为LED的高效发光器.
- 实现高光电发光效率对于实际的LED应用至关重要.
研究的目的:
- 为了提高CsPbBr3NC的光电发光效率.
- 研究异质Ce3+离子对CsPbBr3的光学特性的影响.
主要方法:
- 使用简单的热注射方法合成Ce3+化CsPbBr3NCs.
- 使用超快速短暂吸收和时间分辨光发光谱 (PL) 来分析兴奋剂效应.
主要成果:
- Ce3+ 兴奋剂使 CsPbBr3 NC 的光发光量子产量 (PLQY) 增加到 89%,比未兴奋剂的 NC 提高了两倍.
- 使用Ce3+合的CsPbBr3NCs的LED设备显示电光效率有所改善,外部量子效率 (EQE) 从1.6%上升到4.4%.
结论:
- 不同价值的Ce3+注是一种有效的策略,可以在不损害结构完整性的情况下提高CsPbBr3NC的发光效率.
- 用Ce3+添加的CsPbBr3NC为开发高性能发光二极管提供了一个有前途的途径.
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