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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

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Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
55.8K
Metallic Solids02:37

Metallic Solids

21.0K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.0K
ABC Transporters: Exporter01:31

ABC Transporters: Exporter

6.7K
ATP-binding cassette or ABC transporter is the largest superfamily of integral membrane proteins. The transporters have transmembrane-binding domains (TMDs) and nucleotide-binding domains (NBDs). The TMDs are specific to their substrates, whereas the NBDs are similar to engines that complete ATP hydrolysis to complete the substrate transport. They can be full transporters consisting of two TMDs and NBDs, half transporters with one TMD and NBD, while some encoded with a single TMD or NBD are...
6.7K
ABC Transporters: Importer01:27

ABC Transporters: Importer

3.6K
ATP-binding cassette or ABC transporters are a class of ATP-driven pumps that hydrolyze ATP to move solutes across the membrane. They can be grouped into importers and exporters. While exporters are present in all domains of life, importers exist only in bacteria and some plants.
In bacteria, based on the number of transmembrane helices and the chemical nature of their substrates, the ABC importers can be divided into three types:
3.6K
Structures of Solids02:22

Structures of Solids

18.9K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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六组分分子固体:ABC[D1-(x+y)ExFy]2

Mithun Paul1, Shaunak Chakraborty1, Gautam R Desiraju1

  • 1Solid State and Structural Chemistry Unit, Indian Institute of Science , Bangalore 560012, India.

Journal of the American Chemical Society
|January 23, 2018
PubMed
概括

研究人员开发了一种创建复杂六元分子固体的新方法. 这种方法利用连续的共晶形成和固体溶液结合来构建复杂的超分子结构.

科学领域:

  • 水晶工程
  • 超分子化学
  • 材料科学

背景情况:

  • 设计多元分子固体在控制晶体包装和石化学方面存在重大挑战.
  • 由于缺乏结晶学不等式,以前的策略往往在实现更高阶的共结晶形成方面面临限制.
  • 探索使用低级共晶体作为高级结构的踏板的概念.

研究的目的:

  • 开发一个强大的六元分子固体合成策略.
  • 克服在四级共晶体中遇到的合成限制.
  • 探索将新组件纳入现有的晶格.

主要方法:

  • 开发一种涉及静态四级共晶形成的方案.
  • 利用结晶学不等式进行序列组件替代.
  • 利用化和甲基化素的形状和尺寸相似性 (例如,CRES,BRES,MRES) 来规避合成死胡同.
  • 通过固体溶液的形成加入额外的成分.

主要成果:

  • 一个合成的途径被建立, 从二进制到更高阶的共晶体.
  • 在四级共晶层面发现并克服了合成的死胡同.
  • 已经成功合成了多种五和六成分的分子固体.

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Site-Directed Immobilization of Bone Morphogenetic Protein 2 to Solid Surfaces by Click Chemistry
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  • 第五个和第六个组成部分作为第四个组成部分的固体溶液被纳入.
  • 结论:

    • 开发的战略使复杂的多元分子固体的合理设计和合成成为可能.
    • 利用晶体环境和组件相似性是构建复杂的超分子架构的关键.
    • 这种方法通过精确的分子组装提供了可行的新材料.