通过后合成方法构建共价有机框架的层次结构
Gen Zhang, Masahiko Tsujimoto, Daniel Packwood
1RIKEN CLST-JEOL Collaboration Center , Tsurumi, Yokohama, Kanagawa 230-0045, Japan.
Journal of the American Chemical Society
|January 30, 2018
概括
研究人员开发了一种使用动态共价化学的新后合成方法,以创建等级共价有机框架 (COF). 这种方法可以控制域结构和增强高级应用的材料特性.
科学领域:
- 材料科学
- 纳米技术
- 超分子化学
背景情况:
- 共价有机框架 (COF) 是由有机单元构建的晶体多孔材料.
- 制造具有控制域的等级COF架构是一项挑战.
- 现有的方法缺乏对复杂的COF结构的简单方法.
研究的目的:
- 为层次化COF架构开发一个简单的合成后方法.
- 在COF中控制域结构 (均与核心空).
- 通过层次设计增强COF的功能性质.
主要方法:
- 在固体-液体界面使用动态共价化学 (DCC).
- 准备的2D imine-bonded COF具有不同的芳香基.
- 控制后合成反应动力学以实现不同的域结构.
- 使用固态NMR和TEM进行特征结构.
主要成果:
- 成功制造具有控制的同质和核心外空洞域的层次结构的COF.
- 由于更高的结晶度,合成后的COF表现出比原始相大两倍的BET表面积.
- 精确控制材料的水友性和H2O蒸汽吸附等温.
- 由不同COF领域的分布产生的功能优势.
结论:
- 基于DCC的后合成方法为层次化的COF架构提供了方便的途径.
- 与单相材料相比,层次化COF具有更大的表面积和可调性质.
- 这种方法为设计具有单相材料无法实现的功能的COF开辟了新的途径.
相关概念视频
Covalent Bonds
164.7K
Overview
164.7K
Covalent Bonds
11.9K
Overview
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
11.9K
Network Covalent Solids
16.2K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.2K
Covalently Linked Protein Regulators
9.7K
Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
These groups modify specific amino acids in a protein....
9.7K
Covalently Linked Protein Regulators
2.0K
2.0K
Covalent Bonding and Lewis Structures
63.2K
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
63.2K


