超薄黑色纳米板中的光学可切换光催化
Hui Wang1, Shenlong Jiang1, Wei Shao1
1Hefei National Laboratory for Physical Science at the Microscale, iChEM, Synergetic Innovation Center of Quantum Information and Quantum Physics , University of Science and Technology of China , Hefei , Anhui 230026 , P. R. China.
Journal of the American Chemical Society
|February 17, 2018
概括
超薄黑 (BP) 纳米片在产生活性氧物种 (ROS) 中表现出能量依赖的光学切换效应. 单片氧和基分别在可见光和紫外线下产生,由于子频段结构.
科学领域:
- 材料科学
- 光催化
- 量子化学
背景情况:
- 低维材料在光催化中具有显著的潜力.
- 这些材料中的多体效应,特别是库伦相互作用,往往被忽视.
- 这些相互作用可以导致影响光催化活性的复杂带结构.
研究的目的:
- 研究用于光催化的超薄黑色 (BP) 的光学切换效应.
- 了解多体效应在控制活性氧物种 (ROS) 生成中的作用.
- 通过可控光激发来优化光催化性能的策略.
主要方法:
- 超薄黑 (BP) 纳米片的合成
- 使用可见光和紫外线激发的光催化实验.
- 产生反应性氧物种 (ROS) 产物的分析.
- 基于子带结构和多体效应的理论理解.
主要成果:
- 在BP纳米板中展示了依赖激发能量的光学切换效应.
- 在可见光激发下确定单片氧 (1O2) 为主导的ROS.
- 在紫外线激发下确定基 (•OH) 为主导的ROS.
- 在材料的子带结构中,ROS生成与能量传输和电荷传输过程的相关性.
结论:
- 多体效应在低维材料中显著影响光催化ROS生成.
- 基于光激发能量的BP纳米板表现出可控制的ROS产量.
- 这项工作为光催化中的多体效应提供了基本的见解,并为性能优化提供了途径.
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