具有较大的压电反应的分子铁电中的竞争性素键
Wei-Qiang Liao1,2, Yuan-Yuan Tang2, Peng-Fei Li2
1Institute for Advanced Interdisciplinary Research , Nanjing University of Aeronautics and Astronautics , Nanjing 211106 , P.R. China.
Journal of the American Chemical Society
|February 22, 2018
概括
研究人员开发了一种新的分子铁电,三甲基甲基 (TMCM-CdBr3),其压电系数 (d33) 为139 pC/N. 这一发现为先进的压电应用提供了潜力.
科学领域:
- 材料科学
- 固态物理
- 晶体学
背景情况:
- 分子压电具有灵活性和低重量等优点,但往往缺乏高压电系数.
- 在分子材料中达到与酸 (BTO) 等传统陶可比的压电系数仍然是一个挑战.
研究的目的:
- 呈现一种具有显著压电反应的新型单轴分子铁电.
- 研究素结合在有机-无机混合系统中稳定铁电的作用.
主要方法:
- 三甲基甲基二 (TMCM-CdBr3) 的合成和表征
- 使用已知技术测量压电系数 (d33).
- 对晶体结构和结合的分析,重点是素相互作用.
主要成果:
- TMCM-CdBr3具有139 pC/N的大压电系数 (d33),相当于BTO.
- 这一值明显高于大多数单轴铁电,包括LiNbO3和罗歇尔盐.
- 由于简单的生长和可识别的极轴,该材料具有单晶应用的潜力.
结论:
- 素结合被认为是稳定TMCM-CdBr3铁电性能的关键因素.
- 这项工作为探索具有增强性能的新分子压电开辟了道路.
- 开发的材料有望在灵活的电子设备中实际应用.
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