通过氧化五个环的形成在表面合成印聚合物
Marco Di Giovannantonio1, José I Urgel1, Uliana Beser2
1Empa, Swiss Federal Laboratories for Materials Science and Technology, nanotech@surfaces Laboratory , 8600 Dübendorf , Switzerland.
Journal of the American Chemical Society
|February 24, 2018
概括
研究人员开发了一种新的表面合成方法, 这种技术使用表面辅助的环闭来形成精确的碳纳米结构,具有可调节的电子特性.
科学领域:
- 材料科学
- 有机化学
- 纳米技术
背景情况:
- 表面合成使得通过传统溶液化学无法实现的复杂碳纳米结构的创建成为可能.
- 聚烯是多功能碳基材料,具有可调节的电子特性.
- 采用特定的结构图案,如五个环,可以显著改变材料的特性.
研究的目的:
- 建立基于在表面合成的内单元的一维合聚合物的新合成途径.
- 通过表面辅助的氧化环关闭来研究五个环的形成.
- 描述合成的内聚合物的精确结构和电子特性.
主要方法:
- 在基板上利用表面合成.
- 在聚烯脊柱上使用正甲基,以促进表面辅助的氧化环闭合.
- 使用扫描道显微镜 (STM),非接触性原子力显微镜 (nc-AFM) 和扫描道光谱 (STS) 进行了结果的聚合物,并通过理论计算进行了补充.
主要成果:
- 已经成功合成了由内单元组成的单维合聚合物.
- 通过甲基和基之间的表面辅助氧化环闭合证明了五个环的形成.
- 通过STM,nc-AFM,STS和理论分析证实了原子精确的结构和电子特性.
结论:
- 通过表面合成开发了一种前所未有的内聚合物合成方案.
- 该方法允许精确地将五个环合并到聚合物骨干中.
- 这种方法有可能扩展到其他聚烯和石墨烯纳米带以微调电子特性.
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