在空气中稳定的平面无极性GeSe2用于短波区域的极化敏感光检测
Yusi Yang1,2, Shun-Chang Liu1,3, Wei Yang2
1CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Research Center for Molecular Sciences, CAS Research/Education Center for Excellence in Molecule Science , Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190 , China.
Journal of the American Chemical Society
|March 2, 2018
概括
德二化物 (GeSe2) 是一种具有内平面异性质的新型宽带间隙二维材料. 它在短波区域显示出有前途的极化敏感光检测和出色的空气稳定性.
科学领域:
- 材料科学
- 凝聚物质物理学
- 纳米技术
背景情况:
- 具有平面内异性质的二维 (2D) 材料具有独特的电子和光学特性.
- 现有的异型二维材料是窄带间隙半导体,限制了短波光电子中的应用.
- 需要具有更高稳定性的宽带差异型二维材料.
研究的目的:
- 引入二化物 (GeSe2) 作为一种新型的宽带间隙异构二维材料.
- 系统地研究GeSe2的结构,振动,电气和光学特性.
- 评估 GeSe2 对偏振敏感光电子设备的潜力.
主要方法:
- 理论计算 (密度函数理论) 用于确定电子带结构和表面相互作用能量.
- 试验合成和表征脱皮的GeSe2片.
- 基于GeSe2的光探测器的制造和测试
主要成果:
- GeSe2具有2.74 eV的宽带差和显著的平面光学吸收异性.
- 用GeSe2制造的光探测器在短波区域显示出高度偏振的光响应.
- GeSe2具有特殊的空气稳定性,高氧化吸附激活能量 (2.12 eV),明显超过黑.
结论:
- GeSe2是一个有前途的宽带异性二维材料,用于短波光电子.
- 它的独特特性,包括极化灵敏度和空气稳定性,使其适用于先进的设备应用.
- GeSe2扩大了异构二维材料的范围,为研究和开发开辟了新的途径.
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