热,催化转化基为线性和线性氨基
Xinxin Tang1, Xiangqing Jia1, Zheng Huang1
1State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis , Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences , 345 Lingling Road , Shanghai 200032 , China.
Journal of the American Chemical Society
|March 3, 2018
概括
这项研究引入了一种新型的双催化剂系统,用于高效地将转化为有价值的线性和氨基. 这一突破为从石油原料中生产基本化学构件提供了直接和区域选择的途径.
科学领域:
- 催化剂
- 有机化学
- 石油化学
背景情况:
- 基是石油的主要组成部分,也是化学合成的理想原料.
- 线性化物和氨基是工业化学的重要组成部分.
- 现有的直接转化为线性化物和氨基的方法缺乏.
研究的目的:
- 开发一种有效的方法,直接将n-化物转化为线性化物和氨基.
- 建立一个区域选择性碳化过程的n-.
- 为了证明这种双催化剂系统对氨基甲基化的应用.
主要方法:
- 一个分子双催化剂系统,结合了和催化剂.
- 催化剂使用乙烯或t-丁乙烯作为受体进行转移脱.
- 催化剂使用合成气促进了序列性烯酸异构化-水合.
主要成果:
- 使用Ir/Rh双催化剂系统,特别是以乙烯实现了高区域选择性.
- 该系统显示了高的催化周转率.
- 成功地将轻 (n-,n-) 直接转化为基化物和线性胺.
结论:
- 开发的Ir/Rh双催化剂系统为区域选择性碳化到线性化物提供了有效的途径.
- 这种策略可以从中直接合成有价值的线性化物和氨基.
- 通过提升石油原料,该方法对化学工业具有重大潜力.
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