在有机晶体中引起的反极极结构转变和巨型电阻
Kensuke Kobayashi1, Sachio Horiuchi2, Shoji Ishibashi3
1Condensed Matter Research Center (CMRC) and Photon Factory, Institute of Materials Structure Science , High Energy Accelerator Research Organization (KEK) , Tsukuba 305-0801 , Japan.
Journal of the American Chemical Society
|March 6, 2018
概括
这项研究揭示了有机反铁电晶体由于场诱导的极性切换而表现出巨大的电阻. 这种转变为开发高性能有机电约束材料提供了潜力.
科学领域:
- 材料科学
- 固态物理
- 晶体学
背景情况:
- 有机反铁电是一种在电子领域具有潜在应用的材料.
- 了解它们在外部刺激下的结构转变对于材料设计至关重要.
- 与无机晶体相比,有机晶体中的场诱导过渡较少被探索.
研究的目的:
- 为了研究2-trifluoromethylnaphthimidazole,一个有机反铁电晶体的场所诱导的反极-极结构转换.
- 为了阐明观察到的巨型电阻背后的机制.
- 评估这种转型在开发新型有机电约束材料方面的潜力.
主要方法:
- 在外部电场下使用同步射线衍射分析晶体结构.
- 结构分析侧重于链和相关应变的对齐.
- 电约应变与有机铁电材料和陶材料的比较
主要成果:
- 从一个反极到一个极结构的场所诱导的过渡被观察到.
- 这种转换导致了链的平行对齐.
- 测量了一种巨大的电阻,比有机铁电的压电应变大得多,与陶相比.
- 这种电阻是由于极性切换造成的剪切应变.
结论:
- 有机反铁电的反极-反极结构过渡可以诱导巨大的电阻.
- 与链极性切换相关的剪切应变是这种效应的起源.
- 这种现象为开发高性能电约束性有机材料提供了有前途的途径.
相关概念视频
Ionic Crystal Structures
17.9K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
17.9K
Crystal Field Theory - Octahedral Complexes
31.0K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
31.0K
Crystal Field Theory - Tetrahedral and Square Planar Complexes
48.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
48.7K
Induced Electric Fields
4.7K
The fact that emfs are induced in circuits implies that work is being done on the conduction electrons in the wires. What can possibly be the source of this work? We know that it’s neither a battery nor a magnetic field, as a battery does not have to be present in a circuit where current is induced, and magnetic fields never do any work on moving charges. The source of the work is in fact an electric field that is induced in the wires. For example, if a stationary conductor is placed in a...
4.7K
Structure and Organization of Smooth Muscles
9.0K
Smooth muscle tissue is a type of muscle tissue that can be found lining various vital organs in the human body, including the lungs, blood vessels, digestive tract, and respiratory tract. This type of tissue is responsible for regulating the movements of these organs, playing crucial roles in the functioning of various systems, including the vascular, digestive, respiratory, and urinary systems.
Structure of smooth muscle cell
Smooth muscle cells are spindle-shaped with tapering ends and a...
Structure of smooth muscle cell
Smooth muscle cells are spindle-shaped with tapering ends and a...
9.0K
Prokaryotic Gene Structure and Organization
2.3K
Prokaryotic genomes exhibit a streamlined organization of coding and non-coding regions essential for gene expression and protein synthesis. While coding regions contain the genetic instructions for proteins or functional RNAs, non-coding regions regulate the precise transcription and translation of these genes.Coding Regions: Proteins and RNAsThe primary coding regions, known as structural genes, include sequences transcribed into messenger RNA (mRNA) and ultimately translated into...
2.3K


