来自三角形圆形螺旋体的分子三叶子结
Liang Zhang1, David P August1, Jiankang Zhong1
1School of Chemistry , University of Manchester , Manchester M13 9PL , U.K.
Journal of the American Chemical Society
|March 15, 2018
概括
研究人员用两步的工艺合成了分子三叶子结. 这种方法通过自组合和环闭转化实现了90%的产量,从而创建了复杂的分子结构.
科学领域:
- 超分子化学
- 有机合成
- 化学结晶学
背景情况:
- 分子结是复杂的拓结构,在材料科学和纳米技术中具有潜在的应用.
- 以往合成分子结的方法通常涉及低产量的多步程序.
研究的目的:
- 开发一个有效的两步合成分子三叶草结.
- 作为一个关键的中间体,研究12个组成部分的酸盐的自组装.
主要方法:
- 一个12个组件的三元圆形合物自组装.
- 在螺旋体中间体上的悬挂基链的环闭转化.
- 使用NMR光谱,质谱和X射线晶体学进行表征.
主要成果:
- 一个分子三叶草结的成功两步合成.
- 在三叶草结的总产量达到了90%.
- 通过光谱和晶体分析证实了中间螺旋和最终三叶结的结构.
结论:
- 报告的方法提供了有效的分子三叶草结.
- 这项研究证明了自组合和环闭转化在构建复杂分子拓学的实用性.
- 有特征的三叶草结可以作为探索新功能材料的基础.
相关概念视频
Deformation in a Circular Shaft
933
One of the distinctive characteristics of circular shafts is their ability to maintain their cross-sectional integrity under torsion. In other words, each cross-section continues to exist as a flat, unaltered entity, simply rotating like a solid, rigid slab. To understand the distribution of shearing stress within such a shaft, consider a cylindrical section inside this circular shaft. This section has a length of L and a radius of R, with one end fixed. The radius of the cylindrical section is...
933
Stress Concentrations in Circular Shafts
586
Consider the elastic torsion formula, which applies to a circular shaft with a consistent cross-section. This formula assumes that the shaft's ends are loaded with rigid plates firmly attached. However, in many cases, torques are applied to the shaft through mechanisms like flange couplings or gears, which are connected by keys inserted into keyways. This application method modifies the stress distribution near the point of torque application, causing it to deviate from the distributions...
586
Uniform Circular Motion
22.4K
Uniform circular motion is a specific type of motion in which an object travels in a circle with a constant speed. For example, any point on a propeller spinning at a constant rate is undergoing uniform circular motion. The second, minute, and hour hands of a watch also undergo uniform circular motion. It is hard to believe that points on these rotating objects are actually accelerating, even though the rotation rate is constant. To understand this, we must analyze the motion in terms of...
22.4K
Non-uniform Circular Motion
9.7K
In uniform circular motion, the particle executing circular motion has a constant speed, and the circle is at a fixed radius. However, not all circular motion occurs at a constant speed. A particle can travel in a circle and speed up or slow down, showing an acceleration in the direction of motion. In that case, the motion is called non-uniform circular motion, and an additional acceleration is introduced, which is in the direction tangential to the circle.
For example, such...
For example, such...
9.7K
Dynamics of Circular Motion
25.5K
An object undergoing circular motion, like a race car, is accelerating because it is changing the direction of its velocity. This centrally directed acceleration is called centripetal acceleration. This acceleration acts along the radius of the curved path (thus is also referred to as radial acceleration).
Any acceleration must be produced by some force. Therefore, any force or combination of forces can cause centripetal acceleration. A few examples include the tension in the rope on a...
Any acceleration must be produced by some force. Therefore, any force or combination of forces can cause centripetal acceleration. A few examples include the tension in the rope on a...
25.5K
Molecular Models
43.9K
Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
43.9K


