通过蒸汽辅助转换在表面合成高度定向的薄金属有机框架膜
Erika Virmani1, Julian M Rotter1, Andre Mähringer1
1Department of Chemistry and Center for NanoScience (CeNS) , University of Munich (LMU) , Butenandtstraße 11 (E) , 81377 Munich , Germany.
Journal of the American Chemical Society
|March 16, 2018
概括
蒸汽辅助转换 (VAC) 能够控制面向的,薄的基于的金属有机框架 (MOF) 薄膜的生长. 这种强大的方法对于开发先进的功能性材料和设备至关重要.
科学领域:
- 材料科学
- 纳米技术
- 化学工程
背景情况:
- 控制的薄膜合成对于将多孔晶体框架集成到设备中至关重要.
- 金属有机框架 (MOF) 为各种应用提供可调节的特性.
研究的目的:
- 开发和演示一种蒸汽辅助转换 (VAC) 方法,用于合成基于的MOF的定向薄膜.
- 调查影响MOF膜生长的关键参数,并评估该方法的稳定性.
主要方法:
- 使用VAC合成了UIO-66,UIO-66和UIO-68的薄膜.
- 在造溶液层中的前体在暴露于100°C的溶剂蒸汽后反应了3小时.
- 该过程在裸金,改金和裸表面上进行了测试.
主要成果:
- 已经成功地培养出各种基于的薄膜.
- 在[111]晶体轴上实现了片的定向.
- 关键参数如前体度,调节器,滴量和反应时间被确定为关键.
- 这种VAC方法在不同表面化学性质中被证明是稳固的,产生了面向片.
结论:
- 蒸汽辅助转换 (VAC) 是生产高度定义,定向薄膜的实用且强大的方法.
- 该方法允许通过乙醇吸附证明可访问的孔隙结构.
- VAC提供了一种有价值的新方法,用于制造各种应用的功能MOF薄膜.
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