在 ScF3纳米尺度框架中调整热膨胀的局部对称性破坏
Lei Hu1,2, Feiyu Qin1, Andrea Sanson3
1Department of Physical Chemistry , University of Science and Technology Beijing , Beijing 100083 , China.
Journal of the American Chemical Society
|March 21, 2018
概括
在三化 (ScF3) 纳米尺度框架中实现局部对称性破坏,可以控制接近零的热膨胀. 这种新的方法可以设计出高达675K的特殊热稳定性材料.
科学领域:
- 材料科学
- 固态物理
- 纳米技术
背景情况:
- 不寻常的物质性质通常来自于超出平均晶体结构的局部对称性.
- 负热膨胀在某些固体中是一种罕见的现象.
- 控制热膨胀对于先进的材料应用至关重要.
研究的目的:
- 在三化 (ScF3) 纳米级框架中实现可控制的热膨胀.
- 使用局部对称性破坏设计同位素零热膨胀.
- 调查这种工程热行为的潜在机制.
主要方法:
- 制造纳米尺度的ScF3框架.
- 合成X射线总散射分析原子对分布函数.
- 扩展的X射线吸收细结构 (EXAFS) 光谱.
- 理论计算以证实实验发现.
主要成果:
- 通过局部对称性破坏在ScF3纳米尺度框架中证明可控制的热膨胀.
- 达到同位素零热膨胀,热膨胀系数为+4.0 × 10-8/K,最高达675K.
- 确定局部面扭曲是硬化框架和抑制原子振动的关键.
结论:
- 局部对称破坏是一种有效的策略,用于设计可控制的材料热膨胀.
- 这项研究为设计具有量身定制的热性质的材料提供了新的化学改造途径.
- 这些发现提供了对局部结构和宏观热态的关系的见解.
相关概念视频
Thermal Expansion
5.7K
The expansion of alcohol in a thermometer is one of many commonly encountered examples of thermal expansion, which is the change in size or volume of a given system as its temperature changes. The most visible example is the expansion of hot air. When air is heated, it expands and becomes less dense than the surrounding air, which then exerts an upward force on the hot air to, for example, make steam and smoke rise, and hot air balloons float. The same behavior happens in all liquids and gases,...
5.7K
Thermal expansion and Thermal stress: Problem Solving
2.2K
San Francisco's Golden Gate Bridge is exposed to temperatures ranging from -15 °C to 40 °C. At its coldest, the main span of the bridge is 1275 m long. Assuming that the bridge is made entirely of steel, what is the change in its length between these temperatures?
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55...
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55...
2.2K
Symmetry
222
The equation of an ellipse centered at the origin defines all points whose distances from the center maintain a constant ratio between the horizontal and vertical axes. This equation results in a smooth, closed curve that extends further along the x-axis than the y-axis, giving it a horizontal orientation. Such an ellipse demonstrates three kinds of symmetry: across the x-axis, across the y-axis, and about the origin. These symmetries are essential in understanding the graph's structure and...
222
Fixing Double-strand Breaks
14.9K
The double-stranded structure of DNA has two major advantages. First, it serves as a safe repository of genetic information where one strand serves as the back-up in case the other strand is damaged. Second, the double-helical structure can be wrapped around proteins called histones to form nucleosomes, which can then be tightly wound to form chromosomes. This way, DNA chains up to 2 inches long can be contained within microscopic structures in a cell. A double-stranded break not only damages...
14.9K
Gauss's Law: Planar Symmetry
9.6K
A planar symmetry of charge density is obtained when charges are uniformly spread over a large flat surface. In planar symmetry, all points in a plane parallel to the plane of charge are identical with respect to the charges. Suppose the plane of the charge distribution is the xy-plane, and the electric field at a space point P with coordinates (x, y, z) is to be determined. Since the charge density is the same at all (x, y) - coordinates in the z = 0 plane, by symmetry, the electric field at P...
9.6K
Symmetry in Maxwell's Equations
4.2K
Once the fields have been calculated using Maxwell's four equations, the Lorentz force equation gives the force that the fields exert on a charged particle moving with a certain velocity. The Lorentz force equation combines the force of the electric field and of the magnetic field on the moving charge. Maxwell's equations and the Lorentz force law together encompass all the laws of electricity and magnetism. The symmetry that Maxwell introduced into his mathematical framework may not be...
4.2K


