由小分子组装的独立的纳米晶体材料
Journal of the American Chemical Society
|March 29, 2018
概括
研究人员从有机纳米晶体 (PDIs) 制造出大而稳定的薄膜. 这些坚固的材料具有非线性光学特性,可用于超,是塑料的替代品.
科学领域:
- 材料科学
- 纳米技术
- 有机化学
背景情况:
- 宏观的功能材料通常来自宏分子.
- 从小分子开发替代材料是非常有趣的.
研究的目的:
- 展示从有机纳米晶体制成的厘米大小的独立薄膜的基于溶液的制造方法.
- 研究这些新型纳米结构膜的特性和潜在应用.
主要方法:
- 基于溶液的制造技术
- 有机纳米晶体的组装,特别是二胺 (PDI).
- 薄膜特性,包括机械稳定性,热强度和光学响应.
主要成果:
- 从PDI纳米晶体成功制造出厘米大小的独立薄膜.
- 薄膜具有出色的机械稳定性和热强度 (高达250-300°C),性能优于大多数塑料.
- 已证明非线性光学反应和适用于超膜应用.
结论:
- 从小型有机分子 (纳米晶体) 中有效制造宏观的功能材料.
- 这些基于PDI的薄膜为基于宏分子的材料提供了有前途的替代品或补充.
- 展示的薄膜具有独特的特性,适用于光学和分离技术的先进应用.
相关概念视频
Standing Waves
5.5K
Sometimes waves do not seem to move; rather, they just vibrate in place. Unmoving waves can be seen on the surface of a glass of milk kept in a refrigerator, which is one example of standing waves. Vibrations from the refrigerator motor create waves on the milk that oscillate up and down but do not seem to move across the surface. These waves are formed or created by the superposition of two or more identical moving waves in opposite directions. The waves move through each other, with their...
5.5K
Modes of Standing Waves - I
4.1K
A close look at earthquakes provides evidence for the conditions appropriate for resonance, standing waves, and constructive and destructive interference. A building may vibrate for several seconds with a driving frequency matching the building's natural frequency of vibration; this produces a resonance that results in one building collapsing while the neighboring buildings do not. Often, buildings of a certain height are devastated, while other taller buildings remain intact. This...
4.1K
Modes of Standing Waves: II
1.8K
The starting point for expressing the modes of standing waves is understanding the boundary conditions that the waves must follow. The boundary conditions are derived from the physical understanding of how the standing waves are sustained, that is, how the vibrating particles of the medium behave at the boundaries imposed on them.
For a tube open at one end and closed at the other filled with air, the modes are such that there is always an antinode at the open end and a node at the closed end....
For a tube open at one end and closed at the other filled with air, the modes are such that there is always an antinode at the open end and a node at the closed end....
1.8K
Standing Waves in a Cavity
1.5K
A household microwave and lasers are examples of standing electromagnetic waves in a cavity. When two conducting metal plates are placed parallel at the nodal planes, it creates a cavity where standing waves are formed. The cavity between the two planes is analogous to a stretched string held at the points x = 0 and x = L. Here, the distance 'L' between the two planes must be an integer multiple of half of the wavelength. The wavelengths that satisfy this condition are given by:
1.5K
Standing Electromagnetic Waves
2.3K
Electromagnetic waves can be reflected; the surface of a conductor or a dielectric can act as a reflector. As electric and magnetic fields obey the superposition principle, so do electromagnetic waves. The superposition of an incident wave and a reflected electromagnetic wave produces a standing wave analogous to the standing waves created on a stretched string.
Suppose a sheet of a perfect conductor is placed in the yz-plane, and a linearly polarized electromagnetic wave traveling in the...
Suppose a sheet of a perfect conductor is placed in the yz-plane, and a linearly polarized electromagnetic wave traveling in the...
2.3K
Protein Complex Assembly
16.9K
Proteins can form homomeric complexes with another unit of the same protein or heteromeric complexes with different types. Most protein complexes self-assemble spontaneously via ordered pathways, while some proteins need assembly factors that guide their proper assembly. Despite the crowded intracellular environment, proteins usually interact with their correct partners and form functional complexes.
Many viruses self-assemble into a fully functional unit using the infected host cell to...
Many viruses self-assemble into a fully functional unit using the infected host cell to...
16.9K


