聚合物价值异构体:多
1Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.
Journal of the American Chemical Society
|April 10, 2018
概括
研究人员开发了一种新方法,用独特的中间聚合物,聚烯 (PDOX) 合成聚烯. 这种新的方法为高分子量POX和可重构材料提供了途径.
科学领域:
- 聚合物化学
- 有机合成
- 材料科学
背景情况:
- 由于其结构,聚乙烯 (POX) 的合成具有挑战性.
- 传统的POX生产方法往往是低效的.
- POX具有潜在的有价值的物理特性.
研究的目的:
- 开发一种新型的高分子量聚烯合成策略.
- 探索一个中间聚合物的形成和特性,
- 为了研究聚乙烯的异构化到聚乙烯.
主要方法:
- 使用压力单体Dewar-o-xylylene (DOX) 的价值同位素策略.
- 使用自由基聚合来合成多氧 (PDOX).
- 研究PDOX到POX的热和光诱导异构.
主要成果:
- 通过PDOX成功合成了高分子量聚烯.
- PDOX在它的骨干中形成了高密度的Dewar基.
- 已经证明了PDOX的高效热和光诱导转化为POX.
结论:
- 一种新的价值异构体策略使具有挑战性的聚烯聚合物得以合成.
- 中间的多氧化 (Dewar-o-xylylene) 有助于高效的POX生产.
- 这种方法提供了可调节性质的可重新配置材料.
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