易于多元组合聚合,以非传统的发光聚合物为准,具有易于打开的小异环
Ting Han1,2, Haiqin Deng1,2, Zijie Qiu1,2
1Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute for Advanced Study, Division of Biomedical Engineering and Division of Life Science , The Hong Kong University of Science and Technology , Clear Water Bay, Kowloon , Hong Kong , China.
Journal of the American Chemical Society
|April 10, 2018
概括
研究人员开发了一种新型的聚合方法,用于制造具有小,可打开的亚丁环的功能性聚合物. 这些独特的异环聚合物具有发光和光学特性,可用于电子和生物成像.
科学领域:
- 聚合物化学
- 材料科学
- 有机化学
背景情况:
- 异环聚合物被广泛使用,但由于合成挑战,具有小的可打开环的系统未得到充分探索.
- 目前的研究重点是五或六个成员的异环,在小环功能聚合物开发中留下了一个空白.
研究的目的:
- 开发一个易于合成的功能性聚合物,其中包含小的可打开的异环环.
- 探索含有亚丁的新型聚合物的特性和潜在应用.
主要方法:
- 使用单多组分聚合反应合成以亚丁为基础的聚合物.
- 通过酸介导的环开反应,将亚丁部分转化为胺和胺组.
- 光学和发光性质的描述,包括固态发光和光学透明度.
主要成果:
- 在室温下高效合成功能性聚合物,使用多替代的,富含 heteroatom 的 azetidine 框架.
- 亚丁环成功转化为胺和胺组,产生新的聚合物材料.
- 聚合物表现出内在可见的发光,高光学透明度,可调节的折射率和良好的光模式性.
- 环开放的聚合物被证明是生物成像的溶酶体特异性光探针.
结论:
- 一种易于聚合的策略可以创建含有亚丁的新型聚合物.
- 这些聚合物具有独特的发光和光学特性,适用于先进的电子和光电子设备.
- 在生物成像中的应用有希望.
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