同时合作的J电池和反合作的H电池
Kang Cai1, Jiajun Xie1, Di Zhang1
1Beijing National Laboratory for Molecular Sciences, Centre for Soft Matter Science and Engineering, Key Lab of Polymer Chemistry & Physics of the Ministry of Education, College of Chemistry , Peking University , Beijing 100871 , China.
Journal of the American Chemical Society
|April 13, 2018
概括
化学家们通过竞争的H-和J-聚合物途径探索了超分子自我组合. 了解这些机制可以控制功能超分子系统的构建.
科学领域:
- 超分子化学
- 材料科学
背景情况:
- 了解超分子自我组装对于设计功能性材料至关重要.
- 竞争的组合途径可以导致不同的超分子结构和特性.
研究的目的:
- 研究一个N-异环芳二胺分子的竞争性自我聚合行为.
- 阐明H和J聚合物形成的热力学特征和机制.
- 探索通过分子设计控制自我组装途径的可能性.
主要方法:
- 在不同的条件下对自我聚合的实验观察.
- 数学模型模拟热力学平衡.
- 影响分子包装的硬质因素的分析.
主要成果:
- 在中等驱动力下通过反合作过程形成的H聚合物.
- 通过增强驱动力的合作机制转化为H聚合物.
- 数学模型准确地预测了实验观察结果.
- 反合作途径有利于低/中小聚合物,而合作途径有利于高聚合物.
- 两种途径的共存抑制了高聚合物的形成,除非达到高聚合.
- 分子修饰成功抑制了H聚合,有利于单一的合作J聚合路径.
结论:
- 这项研究揭示了反合作和合作自我组装途径之间的独特相互作用.
- H-和J-聚合物的顺序形成是由增加的自我聚合力驱动的.
- 分子设计可以选择性地控制自我组装路径,使得有针对性的超分子结构形成.
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