在室温下通过无催化剂多元件聚合物从元素硫转化为功能性多氨酸
Tian Tian1, Rongrong Hu1, Ben Zhong Tang1,2
1State Key Laboratory of Luminescent Materials and Devices, Center for Aggregation-Induced Emission , South China University of Technology , Guangzhou 510640 , China.
Journal of the American Chemical Society
|April 25, 2018
概括
研究人员开发了一种新的无催化剂方法,在室温下将硫转化为功能性聚氨酸. 这种高效的工艺为硫的利用提供了可持续的解决方案,并创造了用于检测和清除污染的材料.
科学领域:
- 聚合物化学
- 材料科学
- 环境科学
背景情况:
- 由于硫的丰富性,储存问题和有限的消费,硫利用面临全球性挑战.
- 开发经济高效的硫转化方法对工业和学术界至关重要.
研究的目的:
- 报告一种新的,无催化剂的方法,用于将元素硫转化为功能性聚尿素.
- 探索合成的聚尿素在环境修复中的潜在应用,特别是检测和去除.
主要方法:
- 一种多元组件聚合反应,涉及硫,酸二胺和空气中的二氧化.
- 由此产生的多尿素的结构,分子量和产量的表征.
- 评估聚尿素的离子检测和去除能力.
主要成果:
- 成功合成了16种具有明确结构,高分子量 (高达242,500g/mol) 和高达95%的多尿素.
- 对于检测的聚尿素的高灵敏度 (Ksv = 224,900 L/mol) 和选择性.
- 通过光实时监测,实现了高于99.99%的Hg2+去除效率,以达到饮用水标准.
结论:
- 已经建立了一个高效的室温无催化剂聚合方法,用于将硫转化为多尿素.
- 合成的聚氨酸具有重要的环境应用潜力,包括敏感的检测和有效的水净化.
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