非传统的,安全的,高压可充电电池,使用周期长
Maria Helena Braga1,2, Chandrasekar M Subramaniyam1, Andrew J Murchison1
1Materials Science and Engineering Program and Texas Materials Institute , The University of Texas at Austin , Austin , Texas 78712 , United States.
Journal of the American Chemical Society
|April 25, 2018
概括
这项研究介绍了一种室温完全固态的可充电电池, 它表现出特殊的循环寿命和增加的容量,为储能提供安全,快速充电的替代方案.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 开发安全,高性能固态电池对于下一代储能至关重要.
- 现有的离子电池技术在循环寿命,安全性和能量密度方面面临限制.
- 全固态电解质具有潜在的优势,但需要创新的设计来实现有效的离子传输和稳定性.
研究的目的:
- 为了研究一种新型的室温完全固态可充电电池与双电解质.
- 评估电化学性能,包括循环寿命,容量保留和充/放电特性.
- 了解电池运行过程中电偶电解质中的电极作用.
主要方法:
- 使用阳极,+玻璃电解质,塑化剂和氧化主电极制造全固态电池.
- 电化学测试包括不同速率和电压切断的静电充/放电循环.
- 在循环过程中产生的内部电场下的电解质行为和离子传输机制的分析.
主要成果:
- 在153mA·g-1的电压下实现了超过23000次充/放电循环.
- 在329个循环中显示出585mAh·g-1的容量.
- 在316个循环中,观察到放电电压在4.5和3.7V之间的稳定运行.
结论:
- 配合电解质,包括Li+玻璃和可塑剂,可实现高电压操作和卓越的循环寿命.
- 电解质内的电二极体有助于维持内部电场,提高性能和容量.
- 电池的设计提供了一个安全的快速充电解决方案,具有比传统方法更好的储能能力.
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