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使用非发射型三氨酸连接体构建发光黄金 (I) 盒,该盒经历机色崩成为螺旋复合体
Daniel T Walters1, Reza Babadi Aghakhanpour1, Xian B Powers1
1Department of Chemistry , University of California, Davis , One Shields Avenue , Davis , California 95616 , United States.
Journal of the American Chemical Society
|May 1, 2018
概括
合成了具有独特盒状结构的新发光黄金 (I) 复合物. 机械研磨将蓝色发射晶体转化为绿色发射无形固体,揭示了一种新的机色变化机制.
科学领域:
- 协调化学
- 材料科学
- 固态化学
背景情况:
- 黄金 (I) 复合物以其多样化的结构和发光特性而闻名.
- 机械色变化是固态材料中一个有趣的现象.
- 了解多核黄金复合体中的结构属性关系对于开发新的功能材料至关重要.
研究的目的:
- 合成和表征具有盒状结构的新型发光黄金.
- 在机械研磨过程中研究这些黄金 (I) 复合物的机色行为.
- 阐明观察到的机色变化背后的结构变化和机制.
主要方法:
- 合成和结晶学表征黄金 (I) 复合物,包括单晶X射线衍射.
- 发光晶体的机械研磨.
- 在研磨前和后对固态材料进行光谱分析 (发光).
- 机色产品的结构分析.
主要成果:
- 新型盒状黄金,Au6Triphos4Cl5+,已经成功合成和表征.
- 通过机械研磨发出蓝色的[Au6(Triphos) 4Cl5+晶体,产生了绿色发射的无形固体.
- 这种转化涉及到桥接离子的形成,[μ-Cl{Au3(Triphos) 2}2,以及这种机色变化的拟议机制.
- 确定了蓝色和绿色发射物种的晶体结构.
结论:
- 这项研究表明,在发光黄金中存在独特的机色变化.
- 盒状金可以通过机械力量转化为桥梁螺旋结构,改变它们的发光颜色.
- 这项工作提供了基于多核黄金复合物的机色材料设计的见解.
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